N-Methylaniline → HCID 9944278, compound

Reaction equation

[CH3:1][O:2][C:3]1[CH:14]=[CH:13][C:6](/[CH:7]=[CH:8]/[S:9](Cl)(=[O:11])=[O:10])=[CH:5][CH:4]=1.[CH3:15][NH:16][C:17]1[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=1>>[CH3:1][O:2][C:3]1[CH:14]=[CH:13][C:6](/[CH:7]=[CH:8]/[S:9]([N:16]([CH3:15])[C:17]2[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=2)(=[O:11])=[O:10])=[CH:5][CH:4]=1

Participants

Reactant 2

HCID 7515N-Methylaniline

HCID 12114473HCID 12114473, compound

Product 1

HCID 9944278HCID 9944278, compoundYield 80.9%

Procedure

A solution of (E)-4-methoxystyrylsulfonyl chloride (10 mmol) and N-methyl aniline (10 mmol) was subjected to General Procedure 1, part B. The title compound, melting point 126-129° C., was obtained 80.9% yield.

Sources & evidence

ORD record: ord-f3cb0222c2424723aae33280aca55fd1
Source dataset: uspto-grants-2003_11
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06646009B2

Reaction notes

Loading…