Hydrochloric Acid → CF3(CF2)7CH2CH2Cl

HRID 496960

Reaction equation

[C:1]([C:5]([C:8]([C:11]([C:14]([C:17]([C:20]([C:23]([CH:26]=[CH2:27])([F:25])[F:24])([F:22])[F:21])([F:19])[F:18])([F:16])[F:15])([F:13])[F:12])([F:10])[F:9])([F:7])[F:6])([F:4])([F:3])[F:2].[Al](I)(I)I.[ClH:32]>>[C:1]([C:5]([C:8]([C:11]([C:14]([C:17]([C:20]([C:23]([CH2:26][CH2:27][Cl:32])([F:24])[F:25])([F:21])[F:22])([F:18])[F:19])([F:16])[F:15])([F:13])[F:12])([F:10])[F:9])([F:7])[F:6])([F:4])([F:3])[F:2]

Participants

Reactant 3

HCID 313Hydrochloric Acid

HCID 82222Aluminum iodide

HCID 889901H,1H,2H-Perfluoro-1-decene

Product 1

HCID 85612084CF3(CF2)7CH2CH2Cl

Procedure

The same process as in Example 1 was conducted except that 41 g of CF3(CF2)7CH═CH2, 12 g of CaSO4/C (25/75 mass %) instead of AlI3, and 3.4 g of hydrogen chloride gas instead of 11 g of hydrogen iodide gas were used. CF3(CF2)7CH2CH2Cl was produced at a conversion rate of 1.7% and at a selectivity of 100%.

Sources & evidence

ORD record: ord-5c1d5956ba7047cea384543dee7432df
Source dataset: uspto-grants-2005_09
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06946582B2

Linked notes

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