Chlorotrimethylsilane → (3,5-Dimethylphenyl)trimethylsilane

Reaction equation

Br[C:2]1[CH:3]=[C:4]([CH3:9])[CH:5]=[C:6]([CH3:8])[CH:7]=1.Cl[Si:11]([CH3:14])([CH3:13])[CH3:12]>>[CH3:12][Si:11]([CH3:14])([CH3:13])[C:2]1[CH:3]=[C:4]([CH3:9])[CH:5]=[C:6]([CH3:8])[CH:7]=1

Participants

Reactant 2

HCID 6397Chlorotrimethylsilane

HCID 136357Benzene, 1-bromo-3,5-dimethyl-

Product 1

HCID 2760843(3,5-Dimethylphenyl)trimethylsilane

Procedure

In the same manner as described in preparation 1, 5-bromo-m-xylene was allowed to react with chlorotrimethylsilane, and afforded TSIX. The yield and properties of product are summarized in Table 1.

Workup

customafforded TSIX
customThe yield

Sources & evidence

ORD record: ord-a6e9045e32c049c09013afb37b5d1d71
Source dataset: uspto-grants-1993_09
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05243010

Reaction notes

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