1,1',1''-(Chlorosilylidyne)tris(benzene) → 5-Tripenylsilyl-m-xylene

HRID 5047

Reaction equation

HRID 5047 reaction equation
Br[C:2]1[CH:3]=[C:4]([CH3:9])[CH:5]=[C:6]([CH3:8])[CH:7]=1.Cl[Si:11]([C:24]1[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=1)([C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)[C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1>>[C:24]1([Si:11]([C:12]2[CH:13]=[CH:14][CH:15]=[CH:16][CH:17]=2)([C:18]2[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=2)[C:2]2[CH:3]=[C:4]([CH3:9])[CH:5]=[C:6]([CH3:8])[CH:7]=2)[CH:25]=[CH:26][CH:27]=[CH:28][CH:29]=1

Participants

3

Reactant 2

HCID 64581,1',1''-(Chlorosilylidyne)tris(benzene)HCID 136357Benzene, 1-bromo-3,5-dimethyl-

Product 1

HCID 591719485-Tripenylsilyl-m-xylene

Procedure

In the same manner as described in preparation 1, 5-bromo-m-xylene was allowed to react with chlorotriphenylsilane, and afforded TPSIX. The yield and properties are summarized in Table 1.

Workup

  1. customafforded TPSIX
  2. customThe yield

Sources & evidence

ORD record
ord-55b62a5f55db48bfae40873d928c5459
Source dataset
uspto-grants-1993_09
Patent number
US05243010

Linked notes

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