Propane → Bromine

HRID 51295

Reaction equation

HRID 51295 reaction equation
[CH3:1][CH2:2][CH3:3].[Br:4][Br:5]>>[Br:4][Br:5].[Br:4][CH:2]([CH3:3])[CH3:1].[Br:4][CH2:1][CH2:2][CH3:3]

Participants

5

Conditions

Temperature
270 °C

Procedure

A mixture of propane (6.0 ml/minute) and bromine (Br2 0.30 ml/hour) was passed into a reactor (glass tube ID 0.38″, heating zone length 4″), which was heated to 270° C. The effluent was analyzed by GC/MS. 100% bromine conversion with 88.9% 2-bromopropane selectivity and 11.1% 1-bromopropane selectivity were obtained.

Workup

  1. customwas passed into a reactor
  2. temperature(glass tube ID 0.38″, heating zone length 4″), which

Sources & evidence

ORD record
ord-0ef39192c2a34d6fb98eab6abaa9dad6
Source dataset
uspto-grants-2004_03
Patent number
US06713655B2

Linked notes

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