D-(-)-Fructose → Hexose

HRID 516425

Reaction equation

HRID 516425 reaction equation
[OH:1][CH2:2][C:3]([C@H:5]([C@@H:7]([C@@H:9]([CH2:11][OH:12])[OH:10])[OH:8])[OH:6])=[O:4].[OH-].[Na+]>>[CH2:2]([OH:1])[CH:3]1[O:4][CH:11]([OH:12])[CH:9]([OH:10])[CH:7]([OH:8])[CH:5]1[OH:6]

Participants

3

Reactant 2

HCID 5984D-(-)-FructoseHCID 14798Sodium Hydroxide

Product 1

HCID 206Hexose

Conditions

Temperature
100 °C

Procedure

A 40-% D-fructose solution was adjusted to pH 11 for heating at 100° C. for 90 minutes by a batch-wise process. So as to maintain the pH, an appropriate volume of 4N NaOH was added every 30 minutes.

Workup

  1. temperatureSo as to maintain the pH

Sources & evidence

ORD record
ord-80517fe6eef24a15b56cff8520911c83
Source dataset
uspto-grants-2015_08
Patent number
US09109266B2

Linked notes

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