2-Methylpyridine → HCID 178419142, compound

HRID 522164

Reaction equation

HRID 522164 reaction equation
[CH:1]1([BH:7][CH:8]2[CH2:13][CH2:12][CH2:11][CH2:10][CH2:9]2)[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.[N:14]1[CH:19]=[CH:18][CH:17]=[CH:16][C:15]=1[CH3:20]>C1COCC1>[CH:8]1([BH:7][CH:1]2[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6]2)[CH2:9][CH2:10][CH2:11][CH2:12][CH2:13]1.[N:14]1[CH:19]=[CH:18][CH:17]=[CH:16][C:15]=1[CH3:20]

Participants

4

Reactant 2

HCID 79752-MethylpyridineHCID 15879360CID 15879360

Product 1

HCID 178419142HCID 178419142, compound

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

Under a nitrogen atmosphere, to a THF solution of dicyclohexylborane (8 mL, 1 M) at 0° C., was added picoline (745 mg, 8 mmol). The reaction mixture was allowed to warm room temperature. Generally the dicyclohexylborane-picoline complex is not isolated but used in solution as a hydroboration reagent.

Workup

  1. customGenerally the dicyclohexylborane-picoline complex is not isolated

Sources & evidence

ORD record
ord-ccbe8df3992b40879c1031b67df9ecd2
Source dataset
uspto-grants-2016_05
Patent number
US09328126B2

Linked notes

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