alpha-Thujene → 2-Methyl-5-(1-methylethyl)bicyclo(3.1.0)hexan-2-ol
Reaction equation
[O-:1]O.[CH3:3][C:4]1[CH:8]2[CH2:9][C:7]2([CH:10]([CH3:12])[CH3:11])[CH2:6][CH:5]=1>[Ni]>[CH3:11][CH:10]([C:7]12[CH2:9][CH:8]1[C:4]([OH:1])([CH3:3])[CH2:5][CH2:6]2)[CH3:12]Participants
4
Reactant 2
Product 1
Reagents, catalysts & solvents 1
Procedure
The hydroperoxide resulting from α-thujene can be reduced to 4-hydroxy-β-thujene and can then be hydrogenated, e.g. in the presence of Raney nickel, to give sabinene hydrate.
Sources & evidence
- ORD record
- ord-c8171cd5fd0b4c1a9e57d3f8d8be06ad
- Source dataset
- uspto-grants-1997_04
- Patent number
- US05620569
Reaction notes
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