Galacturonic Acid → Galacturonic Acid

HRID 540981

Reaction equation

HRID 540981 reaction equation
[O:1]=[CH:2][C@@H:3]([C@H:5]([C@H:7]([C@@H:9]([C:11]([O:13][CH3:14])=[O:12])[OH:10])[OH:8])[OH:6])[OH:4].[O:15]=[CH:16][C@@H:17]([C@H:19]([C@H:21]([C@@H:23]([C:25]([OH:27])=[O:26])[OH:24])[OH:22])[OH:20])[OH:18]>>[O:1]=[CH:2][C@@H:3]([C@H:5]([C@H:7]([C@@H:9]([C:11]([O:13][CH3:14])=[O:12])[OH:10])[OH:8])[OH:6])[OH:4].[O:15]=[CH:16][C@@H:17]([C@H:19]([C@H:21]([C@@H:23]([C:25]([OH:27])=[O:26])[OH:24])[OH:22])[OH:20])[OH:18].[O:1]=[CH:2][C@@H:3]([C@H:5]([C@H:7]([C@@H:9]([CH2:11][OH:12])[OH:10])[OH:8])[OH:6])[OH:4]

Participants

5

Reactant 2

HCID 84740Galacturonic AcidHCID 86346375Methyl-o-D-galacturonate

Product 3

HCID 84740Galacturonic AcidHCID 3037556(2R,3S,4S,5R)-2,3,4,5,6-pentahydroxyhexanalHCID 86346375Methyl-o-D-galacturonate

Procedure

Table 3 below indicates approximate ratios of methyl galacturonate to galacturonic acid, and of methyl galacturonate and galacturonic acid to galactose, obtained from 2-D HSQC NMR of Compound G:

Sources & evidence

ORD record
ord-1c1af110fcd64849b9ce646a5673ac5a
Source dataset
uspto-grants-2014_10
Patent number
US08871925B2

Linked notes

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