1-Vinyl-2-trifluoromethyl-2,3,3-trifluorocyclobutane → Benzene, 1-fluoro-2-(trifluoromethyl)-

HRID 580751

Reaction equation

HRID 580751 reaction equation
[CH:1]([CH:3]1[CH2:6][C:5]([F:8])(F)[C:4]1([C:10]([F:13])([F:12])[F:11])F)=[CH2:2]>C1C=CC=CC=1>[F:13][C:10]([F:11])([F:12])[C:4]1[CH:2]=[CH:1][CH:3]=[CH:6][C:5]=1[F:8]

Participants

3

Reactant 1

HCID 201345821-Vinyl-2-trifluoromethyl-2,3,3-trifluorocyclobutane

Product 1

HCID 9807Benzene, 1-fluoro-2-(trifluoromethyl)-Yield 41%

Reagents, catalysts & solvents 1

HCID 241BenzeneSolvent

Procedure

The general procedure was followed using 11.0 g of 1-vinyl-2-trifluoromethyl-2,3,3-trifluorocyclobutane dissolved in 11.15 g of benzene as the liquid feed at a flow rate of 1 ml/hr. Nitrogen was used as the inert carrier. The reactor was charged with 2.0 g of activated carbon. At 400° C. 41% of o-trifluoromethylfluorobenzene was produced.

Workup

  1. additionThe reactor was charged with 2.0 g of activated carbon
  2. customAt 400° C

Sources & evidence

ORD record
ord-39825371865942a4b6ee94c2fdc6ef8a
Source dataset
uspto-grants-1988_06
Patent number
US04754084

Linked notes

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