Acrylic Acid → Isobornyl acrylate acrylic acid methyl acrylate

HRID 606612

Reaction equation

[CH3:1][C@@:2]12[CH:10]([C:11]([C:13]([O-:15])=[O:14])=[CH2:12])[CH2:9][C@H:5]([C:6]1([CH3:8])[CH3:7])[CH2:4][CH2:3]2.[C:16]([O:20][CH3:21])(=[O:19])[CH:17]=[CH2:18].C(O)(=O)C=C.CCCCCCCCCC(C)C.C(C(CCCC)C(OOC(C)(CCC(OOC(=O)C(CC)CCCC)(C)C)C)=O)C>>[CH3:1][C@@:2]12[CH:10]([C:11]([C:13]([O-:15])=[O:14])=[CH2:12])[CH2:9][C@H:5]([C:6]1([CH3:7])[CH3:8])[CH2:4][CH2:3]2.[C:16]([OH:20])(=[O:19])[CH:17]=[CH2:18].[C:16]([O:20][CH3:21])(=[O:19])[CH:17]=[CH2:18]

Participants

Reactant 5

HCID 6581Acrylic Acid

HCID 7294Methyl Acrylate

HCID 234592-Methylundecane

HCID 1144482,5-Dimethyl-2,5-bis(2-ethylhexanoylperoxy)hexane

HCID 92004758Isobomyl acrylate

Product 1

HCID 131728765Isobornyl acrylate acrylic acid methyl acrylate

Procedure

18 g of isobornyl acrylate, 71.1 g of methyl acrylate, 0.9 g of acrylic acid, 90 g of isododecane and 1.2 g of 2,5-bis(2-ethylhexanoylperoxy)-2,5-dimethylhexane were then introduced into the above mixture, still at 90° C. and over 1 hour.

Sources & evidence

ORD record: ord-526b6217ddeb4d10af672d4fdc719ab6
Source dataset: uspto-grants-2011_03
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US07915347B2

Linked notes

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