Phosphoric Acid → Phosphate cerium nitrate

HRID 651416

Reaction equation

HRID 651416 reaction equation
O.O.O=[Al]O[Si](O[Si](O[Al]=O)=O)=O.[P:14](=[O:18])([OH:17])([OH:16])[OH:15].[N+:19]([O-:22])([O-:21])=[O:20].[Ce+3:23].[N+:24]([O-:27])([O-:26])=[O:25].[N+:28]([O-:31])([O-:30])=[O:29]>O>[P:14]([O-:18])([O-:17])([O-:16])=[O:15].[N+:19]([O-:22])([O-:21])=[O:20].[Ce+3:23].[N+:24]([O-:27])([O-:26])=[O:25].[N+:28]([O-:31])([O-:30])=[O:29]

Participants

5

Reactant 3

HCID 1004Phosphoric AcidHCID 24948Cerium nitrateHCID 56841936Bentone

Product 1

HCID 86755301Phosphate cerium nitrate

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

A clay/phosphate/cerium nitrate solution was prepared (according to the general teachings of U.S. Patent 5,190,902) by adding 1403 grams of Theile RC-320 kaolin clay slurry to 591 milliliters of water in a high speed mixer. To this mixture, 192 grams of phosphoric acid was then added. To the resulting system, 440 grams of cerium nitrate solution was added. The slurry formulation was then spray dried and the resulting particles calcined at 650° C. for 30 minutes in a muffle furnace. The calcined particles were then mixed with magnesium oxide in a 50/50 weight percent ratio and the resulting material analyzed by a TGA test that showed a SOx absorption rate of 0.21% per minute for the end product material.

Workup

  1. customThe slurry formulation was then spray dried
  2. additionThe calcined particles were then mixed with magnesium oxide in a 50/50 weight percent ratio

Sources & evidence

ORD record
ord-d2e760398a464c5f964f482743b8b8bc
Source dataset
uspto-grants-2001_08
Patent number
US06281164B1

Linked notes

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