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Cerium nitrate

HCID 24948
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Basic information

CAS
10108-73-3
Standard SMILES
O=[N+]([O-])[O-].O=[N+]([O-])[O-].O=[N+]([O-])[O-].[Ce+3]
InChIKey
HSJPMRKMPBAUAU-UHFFFAOYSA-N
Molecular formula
CeN3O9
Average molar mass
326.13 g/mol
Monoisotopic mass
325.8689

Overview

RN given refers to unspecified cerium salt

Names & identifiers

Preferred name
Cerium nitrate
IUPAC
cerium(3+) trinitrate
English name
cerium trinitrate
Molecular formula
Ce.3HNO3
Molecular weight
326.1307

Names & synonyms

RefChem:575222DTXSID001340641241-339-617309-53-4Cerium nitrateNitric acid, cerium saltCerous nitratecerium(3+);trinitrate10108-73-3CERIUM(III) NITRATECERAMICS-AEium(III) nitrateCe(NO3)3
Show more names
cerum nitrateCITRIUMNITRATECerium(3+) nitrateCerium nitrate, ce(no3)3Cerium nitrate (ce(no3)3)Cerous nitrate [ce(no3)3]Nitric acid, cerium(3+) saltNitric acid, cerium(3+) salt (3:1)Cerous nitrate: (Cerium(III) nitrate)
Nitric acid cerium (3+) salt (3:1)Cerium (III) nitrate hydratecerium(3+) trinitratecerium (III) nitrate7U25VKD7PWCEROUS NITRATE [MI]SCHEMBL35227CEROUS NITRATE [MART.]

Database identifiers

CAS
10108-73-3、17309-53-4
PubChem CID
24948
DTXSID
DTXSID20881414
UNII
7U25VKD7PW
EC Number
233-297-2、241-339-6

Properties

Computed structural properties

Topological polar surface area
189 Ų
Hydrogen bond donors
0
Hydrogen bond acceptors
9
Rotatable bonds
0
Heavy atoms
13
Formal charge
0
Complexity
18.8

Experimental & physicochemical properties

Chemical ClassesMetals -> Rare Earth Metals
Physical DescriptionColorless, deliquescent solid; [Hawley]

Physicochemical properties

Density
1.66 g/cm3 · 1.66 g/cm3(Temp: 25 °C)
vapor pressure
0 Pa · 0Pa at 20℃
solubility
soluble in acetone
form
Solid
color
colorless-red crystals, crystalline
Water Solubility
600 g/L · 600g/L at 20℃
InChI
InChI=1S/Ce.3NO3/c;3*2-1(3)4/q+3;3*-1
InChIKey
HSJPMRKMPBAUAU-UHFFFAOYSA-N
SMILES
[N+]([O-])([O-])=O.[N+]([O-])([O-])=O.[N+]([O-])([O-])=O.[Ce+3]
FDA UNII
7 U25VKD7PW · 7U25VKD7PW
EPA Substance Registry System
Nitric acid, cerium(3+) salt (10108-73-3)

Safety & regulation

Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.

GHS classification

GHS Classification · 6 items

This chemical does not meet GHS hazard criteria for 0.5% (1 of 201) of reports.

Danger

H272 (96%): May intensify fire; oxidizer [Danger Oxidizing liquids; Oxidizing solids]

P210, P220, P264+P265, P273, P280, P305+P351+P338, P305+P354+P338, P317, P337+P317, P370+P378, P391, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 201 reports by companies from 15 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

Hazard information

Regulatory InformationREACH registered substance: Cerium trinitrate (EC: 233-297-2)
Hazards SummaryCaution: strong oxidizer and fire risk; [Hawley] See Cerium. See RARE EARTH METALS and linked occupational diseases.
Hazard Classes and Categories · 2 items

Ox. Sol. 2 (96%)

Met. Corr. 1 (100%)

Safety & protection

Protective Action Criteria (PAC) · 3 items

9.5 [mg/m3]

100 [mg/m3]

620 [mg/m3]

Toxicology

Adverse EffectsFibrogenic - Inducing tissue injury and fibrosis (scarring).

Safety data

Chemistry & industry

Pharmacology

MeSH Pharmacological ClassificationSubstances used on humans and other animals that destroy harmful microorganisms or inhibit their activity. They are distinguished from DISINFECTANTS, which are used on inanimate objects.

Uses & manufacturing

UsesUsed in separation of rare earth elements and as a catalyst; Used in past to make incandescent mantles; [Merck Index]

Applications

UsesCerium trinitrate is used for separation of Ce from other rare earths; catalyst in hydrolysis of phosphoric acid esters; mixture with Th(NO3)4 (1:99) formerly used in manufacture of incandescent mantles.

Preparation methods

PreparationCerium(III) nitrate may be prepared by the action of nitric acid on a cerium(III) salt, followed by crystallization: Ce2(CO3)3 + 6HNO3 → 2Ce(NO3)3 + 3CO2 + 3H2O.

Related reactions

26 records
New reaction record
HRID 6307 reaction equation
HRID 6307As reactantuspto-grants-1993_09
HRID 234866 reaction equation
HRID 234866As productuspto-grants-1997_01
HRID 251752 reaction equation
HRID 251752As reactantuspto-grants-2011_01
HRID 258630 reaction equation
HRID 258630As reactantuspto-grants-1977_07
HRID 555187 reaction equation
HRID 555187As reactantuspto-grants-2011_11
HRID 651416 reaction equation
HRID 651416As reactantuspto-grants-2001_08
HRID 651417 reaction equation
HRID 651417As reactantuspto-grants-2001_08
HRID 1004147 reaction equation
HRID 1004147As reactantuspto-grants-2000_04
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Compound notes

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On this pageBasic informationOverviewNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
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Symbol(GHS)
3 · GHS03,GHS07,GHS09
Signal word
Warning
Hazard statements
272 · H272-H318-H400-H410
Precautionary statements
280 · P280-P273-P305+P351+P338-P310-P391-P501
RIDADR
1477 · 1477
TSCA
TSCA listed
HazardClass
5.1 · 5.1
PackingGroup
II
Toxicity
50 in · LD50 in rats: 290 mg/kg i.p.; 4.2 g/kg orally (Bruce)
REACH Registrations
Active
tsca
TSCA listed
ridadr
1477
Toxicity
LD50 in rats: 290 mg/kg i.p.; 4.2 g/kg orally (Bruce)
Signal word
Warning
Symbol(GHS)
GHS03,GHS07,GHS09
hazard_class
5.1
packing_group
II
Hazard statements
H272-H318-H400-H410
REACH Registrations
Active
Precautionary statements
P280-P273-P305+P351+P338-P310-P391-P501