Ammonia → HCID 70350030, compound

HRID 65195

Reaction equation

HRID 65195 reaction equation
CS[C:3](SC)=[CH:4][N+:5]([O-:7])=[O:6].[CH3:10][N:11]1[CH2:16][CH2:15][NH:14][CH2:13][CH2:12]1.[NH3:17]>ClCC(Cl)(Cl)Cl>[NH2:17][C:3]([N:14]1[CH2:15][CH2:16][N:11]([CH3:10])[CH2:12][CH2:13]1)=[CH:4][N+:5]([O-:7])=[O:6]

Participants

5

Reactant 3

HCID 222AmmoniaHCID 531671-MethylpiperazineHCID 836231,1-Bis(methylthio)-2-nitroethylene

Product 1

HCID 70350030HCID 70350030, compound

Reagents, catalysts & solvents 1

HCID 124181,1,1,2-TetrachloroethaneSolvent

Procedure

An amount of 16.5 g of 1,1-bis-(methylthio)-2-nitroethene is dissolved at high temperature in 100 ml of tetrachloroethane, equimolar amounts of methyl-piperazine are added, the mixture is refluxed over 2 hours; the mass is cooled and anhydrous gaseous ammonia is added to it up to saturation.

Workup

  1. temperaturethe mixture is refluxed over 2 hours
  2. temperaturethe mass is cooled

Sources & evidence

ORD record
ord-67ce7d1c8b6e4df0965b3debb666c260
Source dataset
uspto-grants-1986_09
Patent number
US04613602

Linked notes

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