HuagongsheHuagongshe Chemistry Print Report · For research reference only
Oxalic Acid → HCID 19886321, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Oxalic Acid | HCID 971 | — |
| Reactant | Isopropanol | HCID 3776 | — |
| Reactant | Trifluoroacetic acid | HCID 6422 | — |
| Reactant | 3-(3-Amino-1,2,4-oxadiazol-5-yl)-1-azabicyclo(2.2.1)heptane | HCID 163938 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Solvent | Dichloromethane methanol | HCID 21226129 | — |
| Product | HCID 19886321 | HCID 19886321 | — |
Reaction Steps
The foregoing oxadiazole (135 mg, 0.00039 mol) was stirred with trifluoroacetic acid (0.18 mL, 0.0024 mol) in dichloromethane (6 mL) for 24 hours. The hydrogen oxalate salt had mp 134°-135° C. (propan-2-ol). Rf=0.78 in dichloromethane/methanol (9:1) on alumina plates. Mass Spectrum, m/z 242 for M+ of free base. (Found: C, 53.87; H, 4.90; N, 16.52. C13H14N4O. C2H2O4 requires C, 54.21; H, 4.85; N, 16.86%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05134146 |
| Source dataset | uspto-grants-1992_07 |
| ORD ID | ord-b3091bf1d1f0497e859f22f0ae4c5e0e |
| Source note | uspto-grants-1992_07 |