HCID 178420439, compound → HCID 178527984, compound

HRID 67704

Reaction equation

HRID 67704 reaction equation
C([S:8][C:9]1[N:10]=[N:11][N:12]([CH2:14][C:15]2[NH:19][N:18]=[N:17][N:16]=2)[N:13]=1)C1C=CC=CC=1>[Hg].CN(C=O)C>[NH:16]1[C:15]([CH2:14][N:12]2[N:11]=[N:10][C:9]([SH:8])=[N:13]2)=[N:19][N:18]=[N:17]1

Participants

4

Reactant 1

HCID 178420439HCID 178420439, compound

Product 1

HCID 178527984HCID 178527984, compound

Reagents, catalysts & solvents 2

HCID 23931MercuryCatalystHCID 6228DimethylformamideSolvent

Procedure

5-Benzylthio-2-(1H-tetrazole-5-ylmethyl)-2H-tetrazole, 175 mg., prepared as described above under part C, was dissolved in 40 ml. of distilled DMF and reduced at the mercury pool cathode (14 cm2Hg pool) with a platinium wire anode. The electrodes were separated by a glass frit. The electrolyte was tetraethylammonium perchlorate, 0.1 M in the DMF solution of the substrate. The electrolysis was carried out at -2.7 to -2.85 volts for 500 seconds at -2.80 v. for about 630 seconds.

Workup

  1. custom, prepared
  2. dissolutionwas dissolved in 40 ml
  3. customThe electrodes were separated by a glass frit
  4. waitfor about 630 seconds

Sources & evidence

ORD record
ord-dbfda54e117c45e19392383469be9c01
Source dataset
uspto-grants-1982_08
Patent number
US04346076

Linked notes

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