N-Trimethylsilyl-N-methylacetamide → 1-Methyl-1-(N-methylacetamido)silacyclobutane

HRID 704067

Reaction equation

HRID 704067 reaction equation
Cl[Si:2]1([CH3:6])[CH2:5][CH2:4][CH2:3]1.[CH3:7][N:8]([Si](C)(C)C)[C:9](=[O:11])[CH3:10]>>[CH3:6][Si:2]1([N:8]([CH3:7])[C:9](=[O:11])[CH3:10])[CH2:5][CH2:4][CH2:3]1

Participants

3

Reactant 2

HCID 81953N-Trimethylsilyl-N-methylacetamideHCID 137554Silacyclobutane, 1-chloro-1-methyl-

Product 1

HCID 150659241-Methyl-1-(N-methylacetamido)silacyclobutane

Procedure

To 30.02 g 1-chloro-1-methylsilacyclobutane was added 36.10 g N-methyl-N-(trimethylsilyl)acetamide. The reaction products were fractionally distilled. The title compound was isolated as a clear, colorless fluid with a boiling point of 68°-76° C. at 3.6 mm Hg. The yield was 31.56 g (86%). The product was identified by NMR and mass spectroscopy.

Workup

  1. distillationThe reaction products were fractionally distilled

Sources & evidence

ORD record
ord-b1a50ac77d5a4b2db5988d6d1a87bed9
Source dataset
uspto-grants-1991_01
Patent number
US04985565

Linked notes

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