Aniline → 4-Nitrodiphenylamine

Reaction equation

[NH2:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[N+:8]([C:11]1[CH:16]=[CH:15][C:14](Cl)=[CH:13][CH:12]=1)([O-:10])=[O:9]>>[CH:5]1[CH:6]=[CH:7][C:2]([NH:1][C:14]2[CH:15]=[CH:16][C:11]([N+:8]([O-:10])=[O:9])=[CH:12][CH:13]=2)=[CH:3][CH:4]=1

Participants

Reactant 2

HCID 6115Aniline2×

HCID 74741-Chloro-4-nitrobenzene

Product 1

HCID 132714-Nitrodiphenylamine

Procedure

aniline method, where p-nitro-chlorobenzene and aniline as raw materials react in the presence of a catalyst to produce 4-nitrodiphenylamine, then, 4-nitrodiphenylamine is reduced by sodium sulfide to form 4-aminodiphenylamine;

Sources & evidence

ORD record: ord-3b6de8a0b0db409880422faff950189b
Source dataset: uspto-grants-2006_08
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US07084302B2

Reaction notes

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