Bromoacetyl bromide → Bromoacetyl-5-amino-1,10-phenanthroline

HRID 743493

Reaction equation

HRID 743493 reaction equation
[NH2:1][C:2]1[CH:15]=[C:14]2[C:9]([N:10]=[CH:11][CH:12]=[CH:13]2)=[C:8]2[C:3]=1[CH:4]=[CH:5][CH:6]=[N:7]2.[Br:16][CH2:17][C:18](Br)=[O:19]>C(#N)C>[Br:16][CH2:17][C:18]([C:6]1[CH:5]=[CH:4][C:3]2[C:8](=[C:9]3[C:14](=[CH:15][C:2]=2[NH2:1])[CH:13]=[CH:12][CH:11]=[N:10]3)[N:7]=1)=[O:19]

Participants

4

Reactant 2

HCID 61147Bromoacetyl bromideHCID 6069701,10-Phenanthrolin-5-amine

Product 1

HCID 19424582Bromoacetyl-5-amino-1,10-phenanthroline

Reagents, catalysts & solvents 1

HCID 6342AcetonitrileSolvent2×

Procedure

5-Amino-1,10-phenanthroline (2) (Preparation 1; 1.28 g; 6.54 mmol) was dissolved with heating in 200 ml anhydrous acetonitrile. Into this solution, was added bromoacetyl bromide (Aldrich; 6.60 g; 32.7 mmol) in 7.2 ml anhydrous acetonitrile.

Sources & evidence

ORD record
ord-3a5d35ea945b4913a7bc2bf9ce07d65b
Source dataset
uspto-grants-1996_09
Patent number
US05556949

Linked notes

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