Methanol → Methyl 5-bromo-2-(methylsulfanyl)pyrimidine-4-carboxylate

HRID 820550

Reaction equation

[Br:1][c:2]1[c:3]([C:10](=[O:11])[OH:12])[n:4][c:5]([S:8][CH3:9])[n:6][cH:7]1.[CH3:13][Si:14]([CH:15]=[N+:16]=[N-:17])([CH3:18])[CH3:19].[CH3:20][OH:21]>>[Br:1][c:2]1[c:3]([C:10](=[O:11])[O:12][CH3:13])[n:4][c:5]([S:8][CH3:9])[n:6][cH:7]1

Participants

Reactant 3

HCID 887Methanol

HCID 167693Trimethylsilyldiazomethane

HCID 2917865-Bromo-2-(methylthio)pyrimidine-4-carboxylic Acid

Product 1

HCID 2794729Methyl 5-bromo-2-(methylsulfanyl)pyrimidine-4-carboxylate

Sources & evidence

ORD record: ord-293cbbaf30074fdb90c02d947b5fd5dd
Source dataset: Test data from https://doi.org/10.1039/C8SC04228D
DOI: 10.1039/C8SC04228D

Linked notes

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