Carbonate Ion → 2-Bromo-6-(6-tert-butyl-8-fluoro-1-oxo-1H-phthalazin-2-yl)-benzaldehyde

HRID 826764

Reaction equation

HRID 826764 reaction equation
[Br:1][c:2]1[c:3]([CH:4]=[O:5])[c:6]([Br:10])[cH:7][cH:8][cH:9]1.[C:11]([CH3:12])([CH3:13])([CH3:14])[c:15]1[cH:16][c:17]2[cH:18][n:19][nH:20][c:21](=[O:26])[c:22]2[c:23]([F:25])[cH:24]1.[C:27](=[O:28])([O-:29])[O-:30].[CH3:33][O:34][c:35]1[c:36]2[c:37]([c:38]3[c:39]([cH:40][cH:41]2)[c:42]([O:43][CH3:44])[cH:45][cH:46][n:47]3)[n:48][cH:49][cH:50]1.[Cs+:31].[Cs+:32].[Cu:51][I:52].[O:53]1[CH2:54][CH2:55][O:56][CH2:57][CH2:58]1>>[c:2]1(-[n:20]2[n:19][cH:18][c:17]3[cH:16][c:15]([C:11]([CH3:12])([CH3:13])[CH3:14])[cH:24][c:23]([F:25])[c:22]3[c:21]2=[O:26])[c:3]([CH:4]=[O:5])[c:6]([Br:10])[cH:7][cH:8][cH:9]1

Participants

8

Reactant 7

HCID 19660Carbonate IonHCID 24350Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)HCID 312751,4-DioxaneHCID 104967Cesium cation2×HCID 104622984,7-Dimethoxy-1,10-phenanthrolineHCID 126486412,6-DibromobenzaldehydeHCID 594737656-(tert-Butyl)-8-fluorophthalazin-1(2H)-one

Product 1

HCID 594737882-Bromo-6-(6-tert-butyl-8-fluoro-1-oxo-1H-phthalazin-2-yl)-benzaldehyde

Sources & evidence

ORD record
ord-fa481307f9c845fbaa45bd3b27bd4ce7
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Linked notes

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