Boron trifluoride → Dilauryl Ether

HRID 839716

Reaction equation

HRID 839716 reaction equation
[CH2:1]1[O:3][CH:2]1[CH2:4][Cl:5].[CH2:6]([OH:18])[CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH3:17].B(F)(F)F>>[CH2:6]([O:18][CH2:1][CH2:2][CH2:4][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH3:14])[CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH3:17].[CH2:4]([Cl:5])/[CH:2]=[CH:1]\[OH:3]

Participants

5

Reactant 3

HCID 6356Boron trifluorideHCID 7835EpichlorohydrinHCID 81931-Dodecanol

Product 2

HCID 20667Dilauryl EtherHCID 15676292(Z)-3-chloroprop-1-en-1-ol

Procedure

185 g of glycerol epichlorhydrin are reacted with 1 mole, i.e., 186 g of dodecanol at 75°-80° C in the presence of 1.5 ml of an acetic acid complex containing 36% BF3. Dodecyl ether of polyepichlorohydrin having the following formula is obtained:

Sources & evidence

ORD record
ord-2c8be6aae2d641cb8578068b91f02ba0
Source dataset
uspto-grants-1978_06
Patent number
US04096332

Linked notes

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