1-Dodecanethiol → Ethyl Acrylate

HRID 847415

Reaction equation

HRID 847415 reaction equation
[CH2:1](S)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].CCCC[CH2:18][C:19]([C:23]([O:25]OC(C)(C)C)=[O:24])([CH2:21]C)[CH3:20]>C1(C)C=CC=CC=1>[C:23]([O:25][CH2:1][CH3:2])(=[O:24])[CH:19]=[CH2:21].[C:23]([O:25][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12])(=[O:24])[C:19]([CH3:20])=[CH2:18]

Participants

5

Reactant 2

HCID 81951-DodecanethiolHCID 71359725Tert-butyl 2-ethyl-2-methylheptaneperoxoate

Product 2

HCID 8821Ethyl AcrylateHCID 18510Decyl methacrylate

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

350 g of toluene, 135 g of ethyl acrylate, and 15 g of n-decyl methacrylate were polymerized with stirring in a reaction flask at 50°-60° C. under argon with 0.3 g of dodecyl mercaptan as a regulator and 2 g of t-butyl perneodecanoate as initiator. After about 30 minutes of reaction, the mixture was precipitated in methanol and the polymer was dried under vacuum.

Workup

  1. customAfter about 30 minutes of reaction
  2. customthe mixture was precipitated in methanol
  3. customthe polymer was dried under vacuum

Sources & evidence

ORD record
ord-c2b49c75adc9482d84cd3eef32fdd950
Source dataset
uspto-grants-1992_08
Patent number
US05141993

Linked notes

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