Methacryloyl chloride → 5,5,5-Trifluoro-4-hydroxy-4-(trifluoromethyl)pentan-2-yl methacrylate

HRID 87747

Reaction equation

[C:26]([Cl:27])(=[O:28])[C:29]([CH3:30])=[CH2:31].[CH2:21]([Li:22])[CH2:23][CH2:24][CH3:25].[CH3:1][C:2](=[CH2:3])[C:4]([O-:5])=[O:6].[F:7][C:8]([C:9]([CH2:10][CH:11]([CH3:12])[OH:13])([OH:14])[C:15]([F:16])([F:17])[F:18])([F:19])[F:20]>>[CH3:1][C:2](=[CH2:3])[C:4]([O:5][CH:11]([CH2:10][C:9]([C:8]([F:7])([F:19])[F:20])([OH:14])[C:15]([F:16])([F:17])[F:18])[CH3:12])=[O:6]

Participants

Reactant 4

HCID 13528Methacryloyl chloride

HCID 87595Methacrylate

HCID 1181911,1,1-Trifluoro-2-(trifluoromethyl)-2,4-pentanediol

HCID 178418339Butyllithium

Product 1

HCID 160501385,5,5-Trifluoro-4-hydroxy-4-(trifluoromethyl)pentan-2-yl methacrylate

Sources & evidence

ORD record: ord-815f466059864c2d96cba4cfa1efcfc9
Source dataset: Training data from https://doi.org/10.1039/C8SC04228D (2/10)
DOI: 10.1039/C8SC04228D

Linked notes

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