Ethanol → Ganex E 535

HRID 894306

Reaction equation

HRID 894306 reaction equation
C(O)C.[OH-].[Na+].[CH:6]([N:8]1[CH2:12][CH2:11][CH2:10][C:9]1=[O:13])=[CH2:7].[C:14]([O:17][CH:18]=[CH2:19])(=[O:16])[CH3:15]>C(OCC)C>[CH:6]([N:8]1[CH2:12][CH2:11][CH2:10][C:9]1=[O:13])=[CH2:7].[C:14]([O:17][CH:18]=[CH2:19])(=[O:16])[CH3:15]

Participants

6

Reactant 4

HCID 702EthanolHCID 6917N-vinyl-2-pyrrolidoneHCID 7904Vinyl AcetateHCID 14798Sodium Hydroxide

Product 1

HCID 270885Ganex E 535Yield 95%

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Conditions

Temperature
30 °C

Procedure

Into a 2 liter round bottom flask 800 ml of ethanol, 12.8 g of sodium hydroxide pellets and 80 g of a copolymer composed of 70% N-vinylpyrrolidone and 30% vinyl acetate are introduced. The resulting reaction mixture is maintained with stirring at 30° C. for 2 hours and is then poured into 8 liters of diethyl ether to precipitate the desired polymer. After filtration the polymer is dried under reduced pressure. Yield: 95%.

Workup

  1. additionare introduced
  2. customThe resulting reaction mixture
  3. temperatureis maintained
  4. customto precipitate the desired polymer
  5. filtrationAfter filtration the polymer
  6. customis dried under reduced pressure

Sources & evidence

ORD record
ord-89a3e98d71a44dd59f10265f058e1e6b
Source dataset
uspto-grants-1981_08
Patent number
US04283384

Linked notes

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