6-Quinolinamine, N,N,2-trimethyl- → 6-quinolinamine, 1,2,3,4-tetrahydro-N,N,2-trimethyl-

HRID 918176

Reaction equation

HRID 918176 reaction equation
[CH3:1][N:2]([C:4]1[CH:5]=[C:6]2[C:11](=[CH:12][CH:13]=1)[N:10]=[C:9]([CH3:14])[CH:8]=[CH:7]2)[CH3:3]>[Rh]>[CH3:3][N:2]([C:4]1[CH:5]=[C:6]2[C:11](=[CH:12][CH:13]=1)[NH:10][CH:9]([CH3:14])[CH2:8][CH2:7]2)[CH3:1]

Participants

3

Reactant 1

HCID 667256-Quinolinamine, N,N,2-trimethyl-

Product 1

HCID 214453526-quinolinamine, 1,2,3,4-tetrahydro-N,N,2-trimethyl-

Reagents, catalysts & solvents 1

HCID 23948RhodiumCatalyst

Procedure

6-(N,N-Dimethylamino)quinaldine was reduced with rhodium on carbon to give 6-(N,N-dimethylamino)-2-methyltetrahydroquinoline.

Sources & evidence

ORD record
ord-63dcf43c984343b1a2896b47cbf7b32e
Source dataset
uspto-grants-1976_07
Patent number
US03969463

Linked notes

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