Dichloromethane → 4-Amino-2-(methylsulfanyl)pyrimidine-5-carbaldehyde

HRID 955681

Reaction equation

HRID 955681 reaction equation
[CH2:13]([Al+:14][CH2:15][CH:16]([CH3:17])[CH3:18])[CH:19]([CH3:20])[CH3:21].[CH2:22]1[CH2:25][CH2:24][CH2:23][O:26]1.[Cl:27][CH2:28][Cl:29].[H-:12].[NH2:1][c:2]1[n:3][c:4]([S:10][CH3:11])[n:5][cH:6][c:7]1[C:8]#[N:9]>>[NH2:1][c:2]1[n:3][c:4]([S:10][CH3:11])[n:5][cH:6][c:7]1[CH:8]=[O:26]

Participants

6

Reactant 5

HCID 6344DichloromethaneHCID 8028TetrahydrofuranHCID 166653HydrideHCID 2957574-Amino-2-(methylsulfanyl)pyrimidine-5-carbonitrileHCID 16686348Bis(2-methylpropyl)alumanylium

Product 1

HCID 2957694-Amino-2-(methylsulfanyl)pyrimidine-5-carbaldehyde

Sources & evidence

ORD record
ord-1547ddd1da09423bb3d2fc24ecfdf6a4
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Linked notes

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