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Oxygen → Fluorene

HRID 9744
Notes
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Reaction equation

HRID 9744 reaction equation
[CH:1]1[C:13]2[CH2:12][C:11]3[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=3)[C:5]=2[CH:4]=[CH:3][CH:2]=1.C(ON1C(=O)N(OC(=O)C)C(=O)N(OC(=O)C)C1=O)(=[O:16])C.O=O>C([O-])(=O)C.[Co+2].C([O-])(=O)C.C([O-])(=O)C.[Mn+2].C([O-])(=O)C.C(O)(=O)C>[C:1]1(=[O:16])[C:13]2[C:5]([C:6]3[C:11]([CH:12]=2)=[CH:10][CH:9]=[CH:8][CH:7]=3)=[CH:4][CH:3]=[CH:2]1.[CH:1]1[C:13]2[CH2:12][C:11]3[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=3)[C:5]=2[CH:4]=[CH:3][CH:2]=1
ParticipantsProcedureSources & evidenceReaction notes

Participants

8

Reactant 3

HCID 977OxygenHCID 6853FluoreneHCID 113011241,3,5-Triacetoxy-hexahydro-1,3,5-triazine-2,4,6-trione

Product 2

HCID 6853FluoreneHCID 22281833Fluoreneone

Reagents, catalysts & solvents 3

HCID 6277Cobalt diacetateCatalyst
HCID 12525Manganous AcetateCatalyst
HCID 176Acetic AcidSolvent

Procedure

A mixture of 1.00 g of fluorene, 0.055 g of 1,3,5-triacetoxy-hexahydro-1,3,5-triazine-2,4,6-trione (3% by mole relative to fluorene), 9.0 g of acetic acid, 0.008 g of cobalt(II) acetate.4H2O and 0.007 g of manganese(II) acetate.4H2O was stirred at 120° C. in an atmosphere of oxygene gas (1 atm=0.1 MPa) for 6 hours. The resulting product in the reaction mixture was analyzed by gas chromatography and was found to yield fluorenon in 93% yield at 99% conversion of fluorene.

Sources & evidence

ORD record
ord-580c97f4c2db48c5b59e2f445311d966
Source dataset
uspto-grants-2006_08
DOI
10.6084/m9.figshare.5104873.v1
Patent number
US07091342B2

Reaction notes

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On this pageParticipantsProcedureSources & evidenceReaction notes