Carbon Dioxide → 1,7-Octadien-3-ol
Reaction equation
C=CC=C.O.C(=O)=[O:7].[CH2:9](O)[CH:10]=[CH:11][CH2:12][CH2:13][CH2:14][CH:15]=[CH2:16]>CN(C)C=O>[CH2:9]=[CH:10][CH:11]([OH:7])[CH2:12][CH2:13][CH2:14][CH:15]=[CH2:16]Participants
6
Reactant 4
Product 1
Reagents, catalysts & solvents 1
Procedure
The thus deposited and separated palladium complex was placed again in the autoclave, to which 0.5 mol of 1,3-butadiene, 1 mol of water, 0.6 mol of carbon dioxide, and 63 ml of dimethyl formamide were fed afresh. Then, the reaction was conducted under the same conditions as mentioned above, with the consequence that 0.158 mol of 2,7-octadien-1-ol, and 0.016 mol of 1,7-octadien 3-ol were produced.
Workup
- customseparated palladium complex
Sources & evidence
- ORD record
- ord-92996d6a6ae842e98deb3a833302f9b2
- Source dataset
- uspto-grants-1991_02
- Patent number
- US04990698
Reaction notes
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