Isopropanol → Yttrium(iii) isopropoxide

HRID 982461

Reaction equation

HRID 982461 reaction equation
[Y:1].[H][H].[CH:4]([OH:7])([CH3:6])[CH3:5]>[Zn]>[CH3:5][CH:4]([CH3:6])[O-:7].[Y+3:1].[CH3:5][CH:4]([CH3:6])[O-:7].[CH3:5][CH:4]([CH3:6])[O-:7]

Participants

5

Reactant 3

HCID 3776IsopropanolHCID 23993Yttrium2×HCID 178418361HCID 178418361, compound

Product 1

HCID 11550724Yttrium(iii) isopropoxideYield 10%

Reagents, catalysts & solvents 1

HCID 23994ZincCatalyst

Procedure

The same reaction was done exactly the same way except no zinc was milled with the yttrium. The milled yttrium was reacted with isopropanol in the same way. There was very little evolution of hydrogen and work-up of the reaction solutions gave a yield of less than 10% for yttrium isopropoxide.

Workup

  1. customThe same reaction

Sources & evidence

ORD record
ord-3e9b2309e27c493691fd5b2a7562c2ab
Source dataset
uspto-grants-1991_02
Patent number
US04996300

Linked notes

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