基本情報
- CAS
20548-54-3- 標準SMILES
[Ca+2].[S-2]- InChIKey
AGVJBLHVMNHENQ-UHFFFAOYSA-N- 分子式
- CaS
- 平均分子量
- 72.15 g/mol
- 単同位体質量
- 71.934662
概要
Calcium sulfide is an organic molecular entity.
名称と識別子
- 優先名称
- Calcium Sulfide
- IUPAC
- calcium sulfide
- 現地名
- カルシウムスルフィド
- 英語名
- CALCIUM SULFIDE
- 分子式
- CaHS
- 分子量
- 73.15
名称と別名
Calcium sulphide1MBW07J51QHEPAR SULPHURIS CALCAREUMDTXSID30885140RefChem:54629Hepar sulphuris calcareum 7120Hepar sulfuris 30 Special OrderHepar Sulphuris Calcareum 200ckDTXCID901024539Bestmade Natural Products Hepar SulphurisBestmade Natural Products Calcium Sulfide Hepar Sulph (Calc Sulf)243-873-5
名称をさらに表示
カルシウムスルフィドオルダーマイト硫化カルシウム硫化カルシウム, 99.9% (metals basis excluding Sr), Sr typically 500 ppmBaumolOldhamiteC.I. 77245thioxocalciumPigment White 9Calcium-sulphide-calciumsulfide(cas)C.I. Pigment White 9
20548-54-3calcium monosulfideCalcium SulfideCalcium sulfide (CaS)CRUDE CALCIUM SULFIDEHepar SulfHepar sulfuris calcareumHEPAR SULPH
データベース識別子
- CAS
20548-54-3- PubChem CID
- 10197613
- DTXSID
DTXSID30885140- ChEBI
CHEBI:81055- UNII
- 1MBW07J51Q
- EC Number
- 243-873-5
物性
構造計算による物性
- 極性表面積
- 1 Ų
- 水素結合供与体数
- 0
- 水素結合受容体数
- 1
- 回転可能結合数
- 0
- 重原子数
- 2
- 形式電荷
- 0
- 複雑度
- 0
実験および物理化学的性質
Chemical ClassesMetals -> Metals, Inorganic Compounds
CosmeticsDepilatory
SpringerMaterials Propertiesthermal expansion coefficient
Density2.58 @25 °C
Melting Point2524 °C
Physical DescriptionWhite solid when pure; Crude and luminous forms may be yellowish to pale-grey; Odor of hydrogen sulfide in moist air; [Merck Index] Colorless powder with an odor of rotten eggs; [Alfa Aesar MSDS]
物理化学的性質
- 融点
- 2000 °C · 2000 °C
- 比重(密度)
- 2.6 · 2.6
- 屈折率
- 2.12 · 2.12
- 溶解性
- 2 O; · slightly soluble in H2O; insoluble in ethanol
- 外見
- 粉
- 比重
- 2.5 · 2.5
- 色
- 白い
- 水溶解度
- 水にわずかに溶ける。アルコールに不溶。
- 比熱容量
- 0.65 J/ · Cp(crystal): 0.65 J/(g·K), at 25℃
- 晶系
- 立方
安全と法規制
GHS分類
GHS Classification
Warning
H315: Causes skin irritation [Warning Skin corrosion/irritation]
P261, P264, P264+P265, P271, P273, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P391, P403+P233, P405, and P501 (click each P-code to see the statement)
Danger
H228 (54.9%): Flammable solid [Danger Flammable solids]
P210, P240, P241, P261, P264, P264+P265, P271, P273, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P391, P403+P233, P405, and P501 (click each P-code to see the statement)
危険有害性情報
Regulatory Information
Chemical: Calcium sulfide (CaS)
Calcium sulphide: Does not have an individual approval but may be used under an appropriate group standard
Other Safety InformationIMAP assessments - Soluble Sulfide Salts: Human health tier II assessment
Hazards SummaryOxidizes in dry air and decomposes in moist air; [Merck Index] Decomposed by water; A skin and strong eye irritant; [Alfa Aesar MSDS]
Hazard Classes and Categories
Flam. Sol. 1 (54.9%)
Hazardous to the aquatic environment (acute) - category 1
STOT SE 3
安全と保護具
Protective Action Criteria (PAC)
1.2 [mg/m3]
13 [mg/m3]
79 [mg/m3]
安全データ
- wgk
- 2
- tsca
- TSCA listed
化学と産業
薬理情報
MeSH Pharmacological ClassificationSubstances that prevent infectious agents or organisms from spreading or kill infectious agents in order to prevent the spread of infection.
用途と製造
Uses
Used in phosphors, lubricant additives, and luminous paints; Has been used in wound treatment (veterinary medicine); [Merck Index]
Painting (Pigments, Binders, and Biocides) [Category: Paint]
Household ProductsInformation on 1 consumer products that contain calcium sulphide in the following categories is provided:
Use ClassificationCosmetics -> Depilatory
General Manufacturing InformationCalcium sulfide (CaS): ACTIVE
応用分野
解説硫化カルシウム,CaS(72.14)．酸化カルシウムを赤熱して硫化水素を通じると得られる．無色の立方晶系結晶．密度2.56 g cm－3．2000 ℃ 以上で分解する．乾燥空気中で酸化されてチオ硫酸カルシウムを生じる．湿った空気中では水分と二酸化炭素を吸収して硫化水素を発生する．水に微溶．水溶液は加水分解して硫化水素カルシウムCa(HS)2と水酸化カルシウムを生じ，アルカリ性を示す．酸を作用させると硫化水素を発生する．ほかに四硫化物，五硫化物がある．脱毛作用があるので皮なめしに用いられる．そのほか，潤滑油添加剤，電子エミッター材料，蛍りん光体としてペイントやニスの成分などに用いられる．また，多硫化物は農業用殺虫殺菌剤(石灰硫黄合剤)として用いられる．
天然物の起源Calcium sulfide occurs in nature as the mineral oldhamite. It has several applications. The ‘luminous’ calcium sulfide is used in phosphors, luminous paints and varnishes. Calcium sulfide also is used as an additive to lubri cants; and as a flotation agent in ore extraction.
使用CALCIUM SULFIDE is used in electron emitters. Luminous CaS used for making luminous paints or varnishes.
一般的な説明Crystal structure of CaS is cubic. Electrical conductivity of calcium sufide in the temperature range of 650oC-1000oC was studied in great detail. It was concluded that CaS could be used as a potential electrolyte in a sulfur concentration cell.2
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