オルトチタン酸テトライソプロピル
Titanium isopropoxide
基本情報
- CAS
546-68-9- 標準SMILES
CC(C)[O-].CC(C)[O-].CC(C)[O-].CC(C)[O-].[Ti+4]- InChIKey
VXUYXOFXAQZZMF-UHFFFAOYSA-N- 分子式
- C12H28O4Ti
- 平均分子量
- 284.22 g/mol
- 単同位体質量
- 284.14670568
概要
Tetraisopropyl titanate appears as a water-white to pale-yellow liquid with an odor like isopropyl alcohol. About the same density as water. Vapors heavier than air.
名称と識別子
- 優先名称
- Titanium isopropoxide
- IUPAC
- tetrakis(propan-2-olate);titanium(4+)
- 現地名
- オルトチタン酸テトライソプロピル
- 英語名
- Titanium tetraisopropanolate
- 分子式
- C12H28O4Ti
- 分子量
- 284.22
名称と別名
546-68-9Titanium(IV) isopropoxideTitanium isopropoxideTitanium tetraisopropylateTETRAISOPROPYL TITANATETilcom TIPTTetraisopropoxytitaniumTitanium isopropylateTetraisopropoxytitanium(IV)TetraisopropanolatotitaniumIsopropyl orthotitanateIsopropyl titanate(IV)
名称をさらに表示
オルトチタン酸テトライソプロピルテトラ(イソプロピルオキシ)チタン(IV)テトラ(イソプロポキシ)チタン(IV)テトラキス(イソプロポキシ)チタン(IV)チタンテトライソプロポキシドテトラキス(イソプロピルオキシ)チタン(IV)テトライソプロポキシチタン(IV)チタン酸イソプロピルα-チタン酸テトライソプロピルテトラキスイソプロポキシチタン(IV)チタン(IV)テトラキス(イソプロポキシド)テトライソプロポキシチタンチタン酸テトライソプロピルチタンイソプロピラートチタン(IV)テトライソプロポキシドチタンイソプロポキシドチタン イソプロポキシドチタン酸テトライソプロピル(チタン酸イソプロピル)チタン(IV)イソプロポキシドチタニウムテトライソプロポキシドTi(OiPr)4TITANIUM TETRAISOPROPOXIDETTIPTETRAISOPROPYL ORTHOTITANATEISOPROPYL TITANATETitanium(Ⅳ) isopropoxide
A 1 (titanate)Orgatix TA 10Tetrakis(isopropoxy)titaniumTyzor TPTTetraisopropoxide titaniumIsopropyl alcohol, titanium saltTitanic acid tetraisopropyl esterTitanium tetra-n-propoxide
データベース識別子
- CAS
546-68-9- PubChem CID
- 11026
- DTXSID
DTXSID5027196- ChEBI
CHEBI:139496- UNII
- 76NX7K235Y
- EC Number
- 208-909-6、651-908-4
物性
構造計算による物性
- 極性表面積
- 92.2 Ų
- 水素結合供与体数
- 0
- 水素結合受容体数
- 4
- 回転可能結合数
- 0
- 重原子数
- 17
- 形式電荷
- 0
- 複雑度
- 10.8
実験および物理化学的性質
Chemical ClassesMetals -> Metal Alkoxides
Density
0.9711 @ 20 °C/4 °C
0.9711 @ 20°C
Viscosity2.11 centipoises @ 25 °C (apparent)
Color/Form
Light-yellow liquid
Colorless to light-yellowish fluid
SolubilitySol in anhydrous ethanol, ether, benzene, chloroform
Boiling Point
220 °C @ 760 mm Hg
220 °C @760 [mm Hg]
DecompositionWhen heated to decomposition it emits acrid smoke & irritating fumes.
Melting PointApprox 20 °C
Vapor Density9.8 (AIR= 1)
Food Contact SubstancesFCS -> FDA Inventory of Food Contact Substances Listed in 21 CFR
Refractive IndexIndex of refraction: 1.46
Physical Description
安全と法規制
安全情報は参考情報です。供給元の安全データシート（SDS）、適用法令、専門家による評価に代わるものではありません。
GHS分類
GHS Classification
This chemical does not meet GHS hazard criteria for 1.7% (23 of 1323) of reports.
Danger
H226 (79.8%): Flammable liquid and vapor [Warning Flammable liquids]
P210, P233, P240, P241, P242, P243, P261, P264+P265, P271, P280, P303+P361+P353, P304+P340, P305+P351+P338, P305+P354+P338, P317, P319, P337+P317, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 1323 reports by companies from 37 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Warning
危険有害性情報
Regulatory Information
Chemical: 2-Propanol, titanium(4+) salt
2-Propanol, titanium(4+) salt (4:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 2-Propanol, titanium(4+) salt (4:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
Status: Active Update: 30-11-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/14879
Tetraisopropyl orthotitanate: Does not have an individual approval but may be used under an appropriate group standard
DOT LabelFlammable Liquid
Fire HazardsExcerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible)]:
Fire PotentialMODERATE, WHEN EXPOSED TO HEAT OR FLAME; CAN REACT WITH OXIDIZING MATERIALS
Health HazardsExcerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible)]:
Hazards Summary
Flammable and moisture sensitive; [Merck Index] Irritating to skin and eyes; Oral LD50 (rat) = 7460 mg/kg; [Sax] A strong reducing agent; Rapidly decomposed by water producing isopropyl alcohol; Highly flammable; Fumes in air; May cause skin and eye irritation; [CAMEO] An eye irritant; [eChemPortal: ERMA] An irritant; [MSDSonline] See Titanium. See Isopropyl alcohol.
化学と産業
用途と製造
Uses
Used for heat-resistant surface coatings in paints, lacquers, and plastics; for hardening and cross-linking of epoxy, silicon, urea, melamine, and terephthalate resins and adhesives; and for adhesion of paints, rubber, and plastics to metals; Also used in catalysts, glass surface treatments, flue gas sorbents, controlled-release pesticides, and dental compositions (to bond to enamel); [HSDB] Used to make nano-sized titanium dioxide; [Merck Index]
Painting (Pigments, Binders, and Biocides) [Category: Paint]
HEAT-RESISTANT SURFACE COATINGS IN PAINTS AND PLASTICS
Polymerization catalyst
Ester exchange reactions; adhesion of paints, rubber, and plastics to metals; condensation catalyst
Used for the hardening and cross-linking of epoxy, silicon, urea, melamine, and terephthalate resins; in the manufacture of noncorrodible, high temperature lacquers; in the sol-gel process; as water repellents and adhesive agents (especially with foils); to improve glass surfaces; as a catalyst in olefin polymerization, and for condensation and esterification.
U.S. Production2023: 1,000,000 - <2,500,000 lb
Consumer UsesCatalyst
Industry UsesPigment
Methods of ManufacturingReaction of titanium tetrachloride with isopropanol.
Household ProductsInformation on 1 consumer products that contain Tetraisopropyl titanate in the following categories is provided:
General Manufacturing Information
Petrochemical Manufacturing
2-Propanol, titanium(4+) salt (4:1): ACTIVE
IN FLUE GAS SORBENT
IN ADHESIVE, CONTROLLED-RELEASE PESTICIDE
... IN DENTAL COMPOSITIONS ... TO BOND TO ENAMEL.
応用分野
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