Titanium isopropoxide

0.9711 @ 20 °C/4 °C

0.9711 @ 20°C

Light-yellow liquid

Colorless to light-yellowish fluid

220 °C @ 760 mm Hg

220 °C @760 [mm Hg]

Tetraisopropyl titanate appears as a water-white to pale-yellow liquid with an odor like isopropyl alcohol. About the same density as water. Vapors heavier than air.

Liquid; CBI

Liquid; mp = 18-20 deg C; [Merck Index] Colorless to light yellow liquid; [HSDB] Light yellow liquid; [MSDSonline]

This chemical does not meet GHS hazard criteria for 1.7% (23 of 1323) of reports.

Danger

H226 (79.8%): Flammable liquid and vapor [Warning Flammable liquids]

P210, P233, P240, P241, P242, P243, P261, P264+P265, P271, P280, P303+P361+P353, P304+P340, P305+P351+P338, P305+P354+P338, P317, P319, P337+P317, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 1323 reports by companies from 37 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Warning

Chemical: 2-Propanol, titanium(4+) salt

2-Propanol, titanium(4+) salt (4:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 2-Propanol, titanium(4+) salt (4:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 30-11-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/14879

Tetraisopropyl orthotitanate: Does not have an individual approval but may be used under an appropriate group standard

Flammable and moisture sensitive; [Merck Index] Irritating to skin and eyes; Oral LD50 (rat) = 7460 mg/kg; [Sax] A strong reducing agent; Rapidly decomposed by water producing isopropyl alcohol; Highly flammable; Fumes in air; May cause skin and eye irritation; [CAMEO] An eye irritant; [eChemPortal: ERMA] An irritant; [MSDSonline] See Titanium. See Isopropyl alcohol.

Flam. Liq. 3 (79.8%)

Flammable liquids - Category 3

If material on fire or involved in fire: Do not extinguish fire unless flow can be stopped or safely confined. Use water in flooding quantities as fog. Solid streams of water may be ineffective. Use "alcohol" foam, dry chemical or carbon dioxide. Cool all affected containers with flooding quantities of water. Apply water from as far a distance as possible. Keep run-off water out of sewers and water sources.

SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.

If material not on fire and not involved in fire: Keep sparks, flames, and other sources of ignition away. Keep material out of water sources and sewers. Build dikes to contain flow as necessary. Attempt to stop leak if without undue personnel hazard.

Personnel protection: Keep upwind. Avoid breathing vapors. ... Do not handle broken packages unless wearing appropriate personal protective equipment. Avoid bodily contact with the material.

5.2 [mg/m3]

57 [mg/m3]

340 [mg/m3]

Excerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible)]:

Personnel protection: ... Wear appropriate chemical protective gloves, boots and goggles.

Used for heat-resistant surface coatings in paints, lacquers, and plastics; for hardening and cross-linking of epoxy, silicon, urea, melamine, and terephthalate resins and adhesives; and for adhesion of paints, rubber, and plastics to metals; Also used in catalysts, glass surface treatments, flue gas sorbents, controlled-release pesticides, and dental compositions (to bond to enamel); [HSDB] Used to make nano-sized titanium dioxide; [Merck Index]

Painting (Pigments, Binders, and Biocides) [Category: Paint]

HEAT-RESISTANT SURFACE COATINGS IN PAINTS AND PLASTICS

Polymerization catalyst

Ester exchange reactions; adhesion of paints, rubber, and plastics to metals; condensation catalyst

Used for the hardening and cross-linking of epoxy, silicon, urea, melamine, and terephthalate resins; in the manufacture of noncorrodible, high temperature lacquers; in the sol-gel process; as water repellents and adhesive agents (especially with foils); to improve glass surfaces; as a catalyst in olefin polymerization, and for condensation and esterification.

Petrochemical Manufacturing

2-Propanol, titanium(4+) salt (4:1): ACTIVE

IN FLUE GAS SORBENT

IN ADHESIVE, CONTROLLED-RELEASE PESTICIDE

... IN DENTAL COMPOSITIONS ... TO BOND TO ENAMEL.