Diallyl ether (HCID 11194)

概要

Diallyl ether appears as a liquid with an odor of radishes. Less dense than water. May be toxic by ingestion, skin absorption, and inhalation, and may irritate skin and eyes. Vapors heavier than air. Used to make other chemicals.

名称と識別子

優先名称: Diallyl ether
IUPAC: 3-prop-2-enoxyprop-1-ene
現地名: アリルエーテル
英語名: Allyl ether
分子式: C6H10O
分子量: 98.14

名称と別名

ALLYL ETHERDiallyl etherAllyletherEther, diallyl1-Propene, 3,3'-oxybis-Ether, propenylUNII-GI3WXY29NQGI3WXY29NQNSC 7619EINECS 209-174-4BRN 1736015AI3-02894

名称をさらに表示

アリルエーテル3-(アリルオキシ)-1-プロペンアリルエーテル3,3'-オキシビス(1-プロペン)ビス(2-プロペニル)エーテル4-オキサ-1,6-ヘプタジエン1,1'-オキシビス(2-プロペン)ジアリルエーテルアリルエ-テルAllylic EtherAllylethersether,diallylpropenyletherether,propenylAllyl ether 98%Allyl ether,99%

Allyl ether (8CI)NSC-7619ALLYL ETHER [MI]4-01-00-02086 (Beilstein Handbook Reference)3,3'-oxybis(prop-1-ene)(CH2=CHCH2)2ODTXSID8060321UN 2360

データベース識別子

CAS: 557-40-4
PubChem CID: 11194
DTXSID: DTXSID8060321
UNII: GI3WXY29NQ
EC Number: 209-174-4
Nikkaji: J6.485H

物性

構造計算による物性

XLogP: 1.4
極性表面積: 9.2 Å²
水素結合供与体数: 0
水素結合受容体数: 1
回転可能結合数: 4
重原子数: 7
形式電荷: 0
複雑度: 49.2

実験および物理化学的性質

Chemical ClassesFlammable agents - 3rd degree

SpringerMaterials PropertiesDensity

LogP0.7 (calculated)

DensityRelative density (water = 1): 0.8

SolubilitySolubility in water: none

Flash Point · 2 件

20 °F (NFPA, 2010)

-6 °C

物理化学的性質

融点: -6 °C · -6°C
沸点: 94 °C · 94 °C
比重(密度): 0.803 g/mL · 0.803 g/mL at 25 °C(lit.)
屈折率: 1.415 · 1.415-1.417
闪点: -7 °C · -7 °C
貯蔵温度: Refrigerator (+4°C) + Flammables area
溶解性: 0.3 % · Chloroform, Methanol (Slightly), 0.3% soluble in water, miscible with alcohol and oils.
外見: clear liquid
色: Colorless to Almost colorless
臭い (Odor): Pungent odor, reminiscent of Radish
水溶解度: 不溶性
Merck: 14 · 14,292
InChI: 1S/C6H10O/c1-3-5-7-6-4-2/h3-4H,1-2,5-6H2
InChIKey: ATVJXMYDOSMEPO-UHFFFAOYSA-N
SMILES: C=CCOCC=C
CAS データベース: 557 · 557-40-4(CAS DataBase Reference)
NISTの化学物質情報: 2 · (CH2=CHCH2)2O(557-40-4)
EPAの化学物質情報: 1 · 1-Propene, 3,3'-oxybis- (557-40-4)

化学的性質

化学的特性clear colorless liquid

安全と法規制

GHS分類

GHS Classification · 4 件

Danger

H225 (100%): Highly Flammable liquid and vapor [Danger Flammable liquids]

P210, P233, P240, P241, P242, P243, P261, P262, P264, P264+P265, P270, P271, P280, P301+P317, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P316, P317, P319, P321, P330, P332+P317, P337+P317, P361+P364, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 40 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危険有害性情報

Regulatory Information · 2 件

Chemical: 1-Propene, 3,3'-oxybis-

The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

DOT LabelFlammable Liquid Poison

Fire Hazards · 3 件

Excerpt from ERG Guide 131 [Flammable Liquids - Toxic; polymerization hazard]:

· HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.

Highly flammable. Vapour/air mixtures are explosive. Risk of fire and explosion on contact with acids or oxidizing agents.

Health Hazards · 2 件

Excerpt from ERG Guide 131 [Flammable Liquids - Toxic; polymerization hazard]:

· TOXIC; may be fatal if inhaled, ingested or absorbed through skin.

DOT ID and Guide2360 131P

Reactive GroupEthers

安全と保護具

Fire Fighting · 2 件

Excerpt from ERG Guide 131 [Flammable Liquids - Toxic; polymerization hazard]:

Use water spray, powder, alcohol-resistant foam, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water.

First Aid Measures · 4 件

Fresh air, rest. Refer for medical attention.

Remove contaminated clothes. Rinse and then wash skin with water and soap.

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

Rinse mouth. Refer for medical attention .

Accidental Release Measures · 2 件

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.

First Aid · 2 件

Excerpt from ERG Guide 131 [Flammable Liquids - Toxic; polymerization hazard]:

General First Aid:

Safe StorageFireproof. Separated from acids and oxidants. See Chemical Dangers. Store only if stabilized. Cool. Keep in the dark.

Exposure Control and Personal Protection· Wear positive pressure self-contained breathing apparatus (SCBA).

毒性情報

Exposure RoutesThe substance can be absorbed into the body by inhalation, through the skin and by ingestion.

Signs and Symptoms · 4 件

Cough. Drowsiness. Unconsciousness.

Dry skin. Redness. Pain.

Redness. Pain.

Dullness. Nausea. Drowsiness. Unconsciousness.

ICSC Environmental DataEnvironmental effects from the substance have not been investigated adequately.

安全データ

wgk: 3
tsca: TSCA listed
rtecs: KN7525000
ridadr: UN 2360
毒性: LD50 orally in rats: 0.32 g/kg (Smyth)
hs_code: 2909.19.1800
risk_code: 36/37/38-20/21/22-11
化審法: (2)-2422
消防法: 危-4-1-II
hazard_code: Xn-F,Xn,F
safety_code: 9-36/37/39-33-26-16-45
hazard_class: 3
packing_group: II
Hazard Classifications: Acute Tox. 4 OralEye Irrit. 2Flam. Liq. 2Skin Irrit. 2STOT SE 3
ストレージクラス: 3 - Flammable liquids

化学と産業

用途と製造

General Manufacturing Information1-Propene, 3,3'-oxybis-: ACTIVE

応用分野

一般的な説明A liquid with an odor of radishes. Less dense than water. Flash point 20°F. May be toxic by ingestion, skin absorption, and inhalation, and may irritate skin and eyes. Vapors heavier than air. Used to make other chemicals.