Methanol → 4-Ethyl-4-(Allyloxymethyl)-2,2 dimethyl-1,3 Dioxane
反応式
C([O:4][CH2:5][CH:6]=[CH2:7])C=C.C[O:9][C:10]([O:13]C)([CH3:12])[CH3:11].[C:15]1([CH3:25])[C:16](S(O)(=O)=O)=[CH:17]C=[CH:19][CH:20]=1.CO>C1(C)C=CC=CC=1>[CH2:16]([C:15]1([CH2:25][O:4][CH2:5][CH:6]=[CH2:7])[CH2:20][CH2:19][O:13][C:10]([CH3:12])([CH3:11])[O:9]1)[CH3:17]参加物
6
実験手順
Trimethololpropane monoallyl ether (174 g) was stirred in toluene (400 ml) with dimethoxypropane (110 g) and toluenesulfonic acid (1 g). The reaction mixture was heated until methanol distilled over and heating continued until distillate was no longer collected. Concentration and vacuum distillaiton (bp 85°-95° C., 1 mm Hg) gave the product in 94% yield.
後処理
- distillationdistilled over and
- temperatureheating
- customno longer collected
- concentrationConcentration and vacuum distillaiton (bp 85°-95° C., 1 mm Hg)
- customgave the product in 94% yield
出典と根拠
- ORDレコード
- ord-1b94ba5e1bd94a539154634a2b41fc9f
- 出典データセット
- uspto-grants-1987_02
- 特許番号
- US04640940
反応ノート
読み込み中…