Bis-trimethylbenzoyl phenylphosphine oxide (HCID 164512)

名称と識別子

優先名称: Bis-trimethylbenzoyl phenylphosphine oxide
IUPAC: [phenyl-(2,4,6-trimethylbenzoyl)phosphoryl]-(2,4,6-trimethylphenyl)methanone
現地名: フェニルビス(2,4,6-トリメチルベンゾイル)ホスフィンオキシド
英語名: Phenylbis(2,4,6-trimethylbenzoyl)phosphine oxide
分子式: C26H27O3P
分子量: 418.47

名称と別名

162881-26-7Phenylbis(2,4,6-trimethylbenzoyl)phosphine oxidePhosphine oxide, phenylbis(2,4,6-trimethylbenzoyl)-Bis-trimethylbenzoyl phenylphosphine oxideJOV61FMS35bis(2,4,6-trimethylbenzoyl)phenylphosphine oxideIRGACURE 801phenyl bis(2,4,6-trimethylbenzoyl)-phosphine oxide(Phenylphosphoryl)bis[(2,4,6-trimethylphenyl)methanone]EC 423-340-5Methanone, 1,1'-(phenylphosphinylidene)bis(1-(2,4,6-trimethylphenyl)-(PHENYLPHOSPHORYL)BIS((2,4,6-TRIMETHYLPHENYL)METHANONE)

名称をさらに表示

フェニルビス(2,4,6-トリメチルベンゾイル)ホスフィンオキシドフェニルビス（2，4，6-トリメチルベンゾイル）ホスフィン＝オキシドビストリメチルベンゾイルフェニルホスフィンオキシドビス(メシチルカルボニル)フェニルホスフィンオキシド2,2′-(フェニルホスフィニリデン)ビス(カルボニル)ビス(1,3,5-トリメチルベンゼン)ビス(2,4,6-トリメチルベンゾイル)フェニルホスフィンオキシドフェニルビス(メシチルカルボニル)ホスフィンオキシドイルガキュア819IC-819α,α′-(フェニルホスフィニリデン)ビス(2,4,6-トリメチルベンズアルデヒド)イルガクレ819DWイルガクレ8192,2′-[(フェニルホスフィニリデン)ビスカルボニル]ビス(1,3,5-トリメチルベンゼン)イルガクレI819[フェニル(2,4,6-トリメチルベンゾイル)ホスホリル](2,4,6-トリメチルフェニル)メタノンBAPOIRGACURE 819Photoinitiator 819OMNIRAD 819UV819OMNIRAD 380PhenylbisPI-819Photoinitiator XBPO

Methanone, 1,1'-(phenylphosphinylidene)bis[1-(2,4,6-trimethylphenyl)-RefChem:569435BIS-TRIMETHYLBENZOYL PHENYLPHOSPHINE OXIDE [INCI]423-340-5605-307-9(phenylphosphoryl)bis(mesitylmethanone)DTXSID8044597UNII-JOV61FMS35

データベース識別子

CAS: 162881-26-7
PubChem CID: 164512
DTXSID: DTXSID8044597
ChEMBL: CHEMBL3182971
UNII: JOV61FMS35
EC Number: 423-340-5、605-307-9
Nikkaji: J1.013.677F

物性

構造計算による物性

XLogP: 6
極性表面積: 51.2 Å²
水素結合供与体数: 0
水素結合受容体数: 3
回転可能結合数: 5
重原子数: 30
形式電荷: 0
複雑度: 610

実験および物理化学的性質

CosmeticsCosmetic ingredients (Bis-Trimethylbenzoyl Phenylphosphine Oxide) -> CIR (Cosmetic Ingredient Review)

Physical DescriptionDry Powder; Large Crystals

物理化学的性質

融点: 131 · 131-135 °C(lit.)
沸点: 590 · 590.0±60.0 °C(Predicted)
比重(密度): 1.17 · 1.17±0.1 g/cm3(Predicted)
蒸気圧: 0 Pa · 0Pa at 20℃
貯蔵温度: Sealed in dry,Room Temperature
溶解性: アセトン、アセトニトリル、トルエン、およびヘキサンジオールジアクリレート: 可溶
外見: 粉
色: 淡い黄色から黄色
水溶解度: 100 μg/L · 100μg/L at 20-21℃
化粧品成分の機能: 光安定剤
InChI: InChI=1S/C26H27O3P/c1-16-12-18(3)23(19(4)13-16)25(27)30(29,22-10-8-7-9-11-22)26(28)24-20(5)14-17(2)15-21(24)6/h7-15H,1-6H3
InChIKey: GUCYFKSBFREPBC-UHFFFAOYSA-N
SMILES: P(C1C=CC=CC=1)(=O)(C(C1C(=CC(C)=CC=1C)C)=O)C(C1C(=CC(C)=CC=1C)C)=O
LogP: 5.77 · 5.77-5.8 at 22℃
CAS データベース: 162881 · 162881-26-7
EPAの化学物質情報: Phosphine oxide, phenylbis(2,4,6-trimethylbenzoyl)- (162881-26-7)

安全と法規制

GHS分類

GHS Classification · 6 件

Warning

H317: May cause an allergic skin reaction [Warning Sensitization, Skin]

P261, P272, P273, P280, P302+P352, P321, P333+P317, P362+P364, and P501 (click each P-code to see the statement)

This chemical does not meet GHS hazard criteria for 0.1% (1 of 776) of reports.

Warning

H317 (99.9%): May cause an allergic skin reaction [Warning Sensitization, Skin]

危険有害性情報

Regulatory Information · 5 件

Chemical: Methanone, 1,1â²-(phenylphosphinylidene)bis[1-(2,4,6-trimethylphenyl)-

Methanone, 1,1'-(phenylphosphinylidene)bis[1-(2,4,6-trimethylphenyl)- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Methanone, 1,1'-(phenylphosphinylidene)bis[1-(2,4,6-trimethylphenyl)- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

PMN - indicates a commenced PMN (Pre-Manufacture Notices) substance.

Status: Active Update: 11-10-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/11625

Phosphine oxide, phenylbis(2,4,6-trimethylbenzoyl)-: Does not have an individual approval but may be used under an appropriate group standard

Hazard Classes and Categories · 5 件

Skin Sens. 1 (99.9%)

Skin Sens. 1 (99.8%)

Skin sensitisation - category 1A

Skin sensitization - Category 1A

Skin Sens. 1A

安全データ

wgk: -
tsca: TSCA listed
hs_code: 29319090
risk_code: 43-53
化審法: (3)-4445
hazard_code: Xi
safety_code: 22-24-37-61
Hazard Classifications: Aquatic Chronic 4Skin Sens. 1
ストレージクラス: 11 - Combustible Solids

化学と産業

用途と製造

UsesCIR ingredient: Bis-Trimethylbenzoyl Phenylphosphine Oxide

U.S. Production2023: 100,000 - <250,000 lb

Consumer UsesPhotosensitive agent

Industry UsesPhotosensitive agent

General Manufacturing Information · 2 件

Adhesive Manufacturing

Methanone, 1,1'-(phenylphosphinylidene)bis[1-(2,4,6-trimethylphenyl)-: ACTIVE

応用分野

使用Phenylbis(2,4,6-trimethylbenzoyl)phosphine oxide is a useful research chemical compound.

上流・下流製品情報

上流原料

1,1′-[メチレンビス(4,1-フェニレン)]ビス(2-メチル-2-ヒドロキシ-1-プロパノン)2-イソプロピルチオキサントン

サプライヤー50 社

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]

郑州阿尔法化工有限公司+86-18530059196 · [email protected]

衢州润东化工有限公司0570-8789886 18892685668 · [email protected]

上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]

Career Henan Chemica Co+86-0371-86658258 +86-13203830695 · [email protected]

補足説明 · 2 件

定義本品は、次の化学式で表される有機化合物である。

定義Phenylbis(2,4,6-trimethylbenzoyl)phosphine oxide (PPO) has a local absorption maximum in the visible spectrum at 405 nm and could provide sufficient initiating radicals to crosslink polyamic diacrylate ester in NMP[1]. Phenylbis(2,4,6-trimethylbenzoyl)phosphine oxide (GR-XBPO) could be used as the reductant, and Monoethanolamine as the oxygen inhibition agent. After UV irradiation, oxygen-containing groups (OCGs) on the graphene oxide (GO) plane and edges are largely removed due to the reduction of GO by free radicals generated by photoinitiator decomposition[2].

フェニルビス(2,4,6-トリメチルベンゾイル)ホスフィンオキシド

基本情報