Acetaldehyde → Phosphine oxide, diphenyl(2,4,6-trimethoxybenzoyl)-

HRID 330711

反応式

HRID 330711 の反応式
COC(OC)([C:10]([C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1)=[O:11])C1C=CC=CC=1.C1CCC(O)(C([C:28]2[CH:33]=[CH:32][CH:31]=[CH:30][CH:29]=2)=O)CC1.OC(C)(C)C([C:39]1[CH:44]=[CH:43][CH:42]=[CH:41][CH:40]=1)=O.C[C:48]([OH:62])(C(C1C=CC(OCCO)=CC=1)=O)C.CC(N1C[CH2:80][O:79]CC1)(C(C1C=CC(SC)=CC=1)=O)C.CCC(N(C)C)(C(C1C=CC(N2C[CH2:104][O:103]CC2)=CC=1)=O)CC1C=CC=CC=1.CN(C)C(CC1C=CC(C)=CC=1)(CC)C(C1C=CC(N2CCOCC2)=CC=1)=O.CC1C=C(C)C=C(C)C=1C([P:142](=[O:155])(C1C=CC=CC=1)C1C=CC=CC=1)=O.CC1C=C(C)C=C(C)C=1C(P(=O)(C(=O)C1C(C)=CC(C)=CC=1C)C1C=CC=CC=1)=O.C(=O)C(=O)CCCCCC.C(=O)C.C1C=CC(C(C(OCCOCCOC(C(C2C=CC=CC=2)=O)=O)=O)=O)=CC=1>C1C=C[CH]C=1.C1C=C[CH]C=1.C1C=CN([C]2C(F)=C=C(F)C=C2)C=1.C1C=CN([C]2C(F)=C=C(F)C=C2)C=1.[Ti]>[CH3:104][O:103][C:15]1[CH:14]=[C:13]([O:79][CH3:80])[C:12]([C:10]([P:142]([C:28]2[CH:29]=[CH:30][CH:31]=[CH:32][CH:33]=2)([C:39]2[CH:40]=[CH:41][CH:42]=[CH:43][CH:44]=2)=[O:155])=[O:11])=[C:17]([O:62][CH3:48])[CH:16]=1

参加物

14

反応物 12

HCID 177AcetaldehydeHCID 703551-Hydroxycyclohexyl phenyl ketoneHCID 819842-Hydroxy-2-methyl-1-phenylpropan-1-oneHCID 861712-Benzyl-2-(dimethylamino)-1-(4-(morpholin-4-yl)phenyl)butan-1-oneHCID 862662-Hydroxy-1-(4-(hydroxyethoxy)phenyl)-2-methyl-1-propanoneHCID 905712,2-Dimethoxy-2-phenylacetophenoneHCID 923872-Methyl-1-(4-(methylthio)phenyl)-2-morpholino-1-propanoneHCID 142756Octanal, 2-oxo-HCID 164512Bis-trimethylbenzoyl phenylphosphine oxideHCID 1664802,4,6-Trimethylbenzoyl diphenylphosphine oxide2 回HCID 220197551-Butanone, 2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(4-morpholinyl)phenyl]-HCID 60004985Benzeneacetic acid, alpha-oxo-, 1,1'-(oxydi-2,1-ethanediyl) ester

生成物 1

HCID 16051725Phosphine oxide, diphenyl(2,4,6-trimethoxybenzoyl)-

試薬・触媒・溶媒 1

HCID 178505935HCID 178505935、化合物触媒

実験手順

Examples of commercially available radical photopolymerization initiator include IRGACURE 651 (2,2-dimethoxy-1,2-diphenyl ethane-1-on), IRGACURE 184 (1-hydroxycyclohexyl-phenyl-ketone), DAROCUR 1173 (2-hydroxy-2-methyl-1-phenyl-propane-1-on), IRGACURE 2959 (1-[4-(2-hydroxyethoxy)-phenyl]-2-hydroxy-2-methyl-1-propane-1-on), IRGACURE 127 (2-hydroxy-1-{4-[4-(2-hydroxy-2-methyl-propnyl)-benzyl]phenyl}-2-methyl-propane-1-on, IRGACURE 907 (2-methyl-1-(4-methyl thiophenyl)-2-morpholinopropane-1-on), IRGACURE 369 (2-benzyl-2-dimethylamino-1-(4-morpholinophenyl)-butanone-1), IRGACURE 379 (2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(4-morpholinyl)phenyl]-1-butanone), DAROCUR TPO (2,4,6-trimethylbenzoyl-diphenyl-phosphine oxide), IRGACURE 819 (bis(2,4,6-trimethylbenzoyl)-phenyl phosphine oxide), IRGACURE 784 (bis(eta-5-2,4-cyclopentadiene-1-yl)-bis(2,6-difluoro-3-(1H-pyrrole-1-yl)-phenyl)titanium), IRGACURE OXE 01 (1.2-octanedione, 1-[4-(phenylthio)-, 2-(o-benzoyloxime)]), IRGACURE OXE 02 (ethanone, 1-[9-ethyl-6-(2-methylbenzoyl)-9H-carbazole-3-yl]-, 1-(o-acetyloxime)), and IRGACURE 754 (mixture of oxyphenyl acetic acid, 2-[2-oxo-2-phenylacetoxyethoxy]ethyl ester and oxyphenyl acetic acid, 2-(2-hydroxyethoxy)ethyl ester)(all produced by BASF); Speedcure TPO (produced by Lambson), KAYACURE DETX-S (2,4-diethylthioxantone) (produced by Nippon Kayaku Co., Ltd.); Lucirin TPO, LR8893, LR8970 (produced by BASF); Ubecryl P36 (produced by UCB), and the like.

後処理

  1. customall produced by BASF)

出典と根拠

ORDレコード
ord-00df0ac85e2c4189a8ec3073bb502d23
出典データセット
uspto-grants-2014_11
特許番号
US08876274B2

関連ノート

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