トリメトキシフェニルシラン

Trimethoxyphenylsilane

HCID 18137CAS 2996-92-1

基本情報

標準SMILES
CO[Si](OC)(OC)c1ccccc1
InChIKey
ZNOCGWVLWPVKAO-UHFFFAOYSA-N
分子式
C9H14O3Si
平均分子量
198.29 g/mol
単同位体質量
198.07122084

名称と識別子

優先名称
Trimethoxyphenylsilane
IUPAC
trimethoxy(phenyl)silane
現地名
トリメトキシフェニルシラン
英語名
Trimethoxyphenylsilane
分子式
C9H14O3Si
分子量
198.29

名称と別名

Phenyltrimethoxysilane2996-92-1TrimethoxyphenylsilaneSilane, trimethoxyphenyl-DTXSID504070021TQE746S9NSC-93925DTXCID3020700RefChem:861841221-066-9trimethoxy(phenyl)silane(Trimethoxysilyl)benzene
名称をさらに表示
トリメトキシフェニルシラントリメトキシシリルベンゼンフェニルトリメトキシシラントリメトキシ(フェニル)シランフェニルトリメトキシシラン, 97%(トリメトキシシリル)ベンゼンモノフェニルトリメトキシシラン4-[3-メトキシ-2-(4-メトキシ-4-オキソブタンアミド)-3-オキソプロピル]フェニル 1-メチル ブタンジオアート4-[[2-[4-(4-メトキシ-1,4-ジオキソブトキシ)フェニル]-1-(メトキシカルボニル)エチル]アミノ]-4-オキソブタン酸メチルTrimethoxyphenyLKH-631trimethoxyphenyl-silanPhenyltriMethoxysilane, 85% 250MLX170CP0330HD-127
SILANE, PHENYLTRIMETHOXY-A 153C9H14O3SiMFCD00025689s1375089885-26-7EINECS 221-066-9NSC 93925

データベース識別子

CAS
2996-92-1
PubChem CID
18137
DTXSID
DTXSID5040700
ChEMBL
CHEMBL1903982
UNII
21TQE746S9
EC Number
221-066-9
Nikkaji
J48.157B

物性

構造計算による物性

極性表面積
27.7 Ų
水素結合供与体数
0
水素結合受容体数
3
回転可能結合数
4
重原子数
13

実験および物理化学的性質

Density1.062 @25 °C
Physical Description · 2 件

Liquid

Clear liquid; [Acros Organics MSDS]

Kovats Retention Index1171.1

物理化学的性質

融点
-25 °C · -25°C
沸点
233 °C · 233 °C(lit.)
比重(密度)
1.062 g/mL · 1.062 g/mL at 25 °C(lit.)
蒸気圧
0 · 0-12790Pa at 20-25℃
屈折率
20 · n20/D 1.468(lit.)
闪点
99 °F · 99 °F

化学的性質

化学的特性Colorless transparent liquid

安全と法規制

GHS分類

GHS Classification · 6 件

This chemical does not meet GHS hazard criteria for 2% (5 of 252) of reports.

Warning

H226 (60.7%): Flammable liquid and vapor [Warning Flammable liquids];H302 (70.2%): Harmful if swallowed [Warning Acute toxicity, oral];H315 (50.4%): Causes skin irritation [Warning Skin corrosion/irritation];H319 (27.8%): Causes serious eye irritation [Warning Serious eye damage/eye irritation];H335 (17.5%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation];H373 (65.1%): May causes damage to organs through prolonged or repeated exposure [Warning Specific target organ toxicity, repeated exposure]

P210, P233, P240, P241, P242, P243, P260, P261, P264, P264+P265, P270, P271, P280, P301+P317, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P319, P321, P330, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 252 reports by companies from 14 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.;Reported as not meeting GHS hazard criteria per 5 of 252 reports by companies.;There are 13 notifications provided by 247 of 252 reports by companies with hazard statement code(s).;Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

危険有害性情報

Regulatory Information · 4 件

Chemical: Silane, trimethoxyphenyl-

Benzene, (trimethoxysilyl)- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Benzene, (trimethoxysilyl)- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 03-12-2021 https://echa.europa.eu/registration-dossier/-/registered-dossier/14391

Silane, trimethoxyphenyl-: Does not have an individual approval but may be used under an appropriate group standard

Other Safety InformationEvaluation - Chemicals that are unlikely to require further regulation to manage risks to environment
Hazards Summary · 1 件

Intravenous LD50 (mouse) = 180 mg/kg; [RTECS] Histopathological changes of the kidney, urinary bladder, and jejunum observed in oral study of rats at 250 mg/kg/day; No evidence of reproductive or developmental toxicity; [EPA - TSCATS] Prolonged or repeated ingestion exposure may cause urinary bladder injury; [ECHA REACH Registrations] Reacts with water evolving methanol; An irritant; [Acros Organics MSDS] A skin and strong eye irritant; [Alfa Aesar MSDS] See Methyl alcohol. See Isobutyltrimethoxysilane.

Hazard Classes and CategoriesFlam. Liq. 3 (60.7%);Acute Tox. 4 (70.2%);Skin Irrit. 2 (50.4%);Eye Irrit. 2 (27.8%);STOT SE 3 (17.5%);STOT RE 2 (65.1%)

安全と保護具

Protective Action Criteria (PAC) · 3 件

0.59 [mg/m3]

6.5 [mg/m3]

39 [mg/m3]

法規制情報

Regulatory Information · 4 件

Chemical: Silane, trimethoxyphenyl-

Benzene, (trimethoxysilyl)- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Benzene, (trimethoxysilyl)- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 03-12-2021 https://echa.europa.eu/registration-dossier/-/registered-dossier/14391

Silane, trimethoxyphenyl-: Does not have an individual approval but may be used under an appropriate group standard

安全データ

F
10-21
wgk
3
tsca
TSCA listed
rtecs
VV5252000
ridadr
UN 1992 3/PG 3
hs_code
29319090

化学と産業

用途と製造

Uses · 2 件

Used to make fine and large scale chemicals, coatings, non-metal surface treatment products, sealants-adhesives, in mold making, and as a laboratory reagent; [ECHA REACH Registrations]

Molding and Core Making [Category: Foundry];Painting (Pigments, Binders, and Biocides) [Category: Paint];Working with Glues and Adhesives [Category: Other]

U.S. Production2023: 5,000,000 - <10,000,000 lb;2022: 5,000,000 - <10,000,000 lb;2021: 5,000,000 - <10,000,000 lb;2020: 5,000,000 - <10,000,000 lb
Industry UsesHeat stabilizer;Intermediate
General Manufacturing Information · 2 件

All Other Chemical Product and Preparation Manufacturing;Paint and Coating Manufacturing;All Other Basic Inorganic Chemical Manufacturing

Benzene, (trimethoxysilyl)-: ACTIVE

応用分野

使用Phenyltrimethoxysilane is used for nanoelectronics and material science research. It is used as crosslinking agent for silicone resin and to produce polymer organic silicon compound.

一般的な説明Trimethoxyphenylsilane (TMPS) is an organotrialkoxysilane that is used as a functional monomer in the sol-gel processing.

調製方法

純化方法Fractionate it through an efficient column but note that it forms an azeotrope with MeOH which is a likely impurity. [Kantor J Am Chem Soc 75 2712 1953 Beilstein 16 IV 1556.]

サプライヤー50 社

常州市弘裕化工有限公司0519-89996110 13813691203 · [email protected]
郑州阿尔法化工有限公司+86-18530059196 · [email protected]
湖北永阔科技有限公司027-59223108 15972152991 · [email protected]
湖北科孚乐材料科技有限公司027-84459282 13720265353 · [email protected]
广州纳珑化工有限公司13192879270; 13192879270 · [email protected]

関連反応

41 件

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