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Hydrochloric Acid → Ethylimidazolium phenol salt

HRID 76209
ノート
印刷プレビュー

反応式

HRID 76209 の反応式
[C:1]1([Si](OC)(OC)OC)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.C([O:16][Si](O[CH2:25][CH3:26])(OCC)OCC)C.C[Si](OCC)(OCC)OCC.C(OCO[Si](CCC1C=CC=CC=1)(OC)OC)(C)(C)C.Cl.C(OCC(O)C)C.C([C:68]1[NH:69][CH:70]=[CH:71][N:72]=1)C>O.C(O)C.CC(C)=O>[C:1]1([OH:16])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[CH2:70]([N+:69]1[CH:26]=[CH:25][NH:72][CH:68]=1)[CH3:71]
参加物実験手順後処理出典と根拠反応ノート

参加物

11

反応物 7

HCID 313Hydrochloric Acid2 回HCID 6517TetraethoxysilaneHCID 152871-Ethoxy-2-propanolHCID 16241TriethoxymethylsilaneHCID 18137TrimethoxyphenylsilaneHCID 661302-EthylimidazoleHCID 67001992Tert-butoxyphenylethyltrimethoxysilane

生成物

1
HCID 131731792Ethylimidazolium phenol salt

試薬・触媒・溶媒 3

HCID 180Acetone溶媒HCID 702Ethanol溶媒HCID 962Water溶媒

実験手順

4.99 g of phenyltrimethoxysilane, 67.99 g of tetraethoxysilane, 26.90 g of methyltriethoxysilane, 0.17 g of tert-butoxyphenylethyltrimethoxysilane, and 150 g of acetone were charged into a 500 mL flask to be dissolved and the resultant mixed solution was warmed while stirring the mixed solution with a magnetic stirrer to reflux. Next, 33.07 g of a 0.01 M hydrochloric acid aqueous solution was added to the mixed solution. The reaction was carried out for 240 minutes and then the resultant reaction solution was cooled down to room temperature. Then, 200 g of propylene glycol monoethyl ether was added to the reaction solution, and ethanol, water and hydrochloric acid being reaction by-products were distilled off under reduced pressure to obtain a hydrolysis-condensation product. To the hydrolysis-condensation product, 0.05 g of ethylimidazole was added to obtain an ethylimidazolium phenol salt-containing Si polymer. The obtained polymer corresponded to a polymer having four types of unit structures of Formula (3-18). The molecular weight Mw of the obtained polymer measured by GPC was found to be 1,500 in terms of polystyrene.

後処理

  1. dissolutionto be dissolved
  2. additionthe resultant mixed solution
  3. temperaturewas warmed
  4. temperatureto reflux
  5. customthe resultant reaction solution
  6. distillationwere distilled off under reduced pressure
  7. customto obtain a hydrolysis-condensation product

出典と根拠

ORDレコード
ord-39ee17805ebf4d2798c4eb3fd69ec3c2
出典データセット
uspto-grants-2014_09
DOI
10.6084/m9.figshare.5104873.v1
特許番号
US08835093B2

反応ノート

読み込み中…

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