ビニルメチルスルホン

Methyl vinyl sulfone

HCID 19354

基本情報

CAS
3680-02-2
標準SMILES
C=CS(C)(=O)=O
InChIKey
WUIJTQZXUURFQU-UHFFFAOYSA-N
分子式
C3H6O2S
平均分子量
106.15 g/mol
単同位体質量
106.00885043

概要

Methyl vinyl sulfone is a clear pale yellow liquid. (NTP, 1992)

名称と識別子

優先名称
Methyl vinyl sulfone
IUPAC
1-methylsulfonylethene
現地名
ビニルメチルスルホン
英語名
Methyl vinyl sulfone
分子式
C3H6O2S
分子量
106.14

名称と別名

Methyl vinyl sulfone3680-02-2Ethene, (methylsulfonyl)-Methyl vinyl sulphoneSULFONE, METHYL VINYLURI 718T6N4PU5BSHNSC-518304DTXSID1031628URI-718RefChem:818119DTXCID9011628
名称をさらに表示
メチルビニルスルホンエテニルメチルスルホンメチルエテニルスルホンビニルメチルスルホンメタンスルホニルエテン(Methylsulfonyl)etheneDK762sulfone,methylvinyl(methylsulfonyl)-ethen
222-958-0methanesulfonylethenevinyl methyl sulfone1-methylsulfonylethenemethyl vinylsulfoneMethylvinylsulfoneethenyl methyl sulfoneMethyl vinyl sulfphone

データベース識別子

CAS
3680-02-2
PubChem CID
19354
DTXSID
DTXSID1031628
ChEMBL
CHEMBL163849
UNII
T6N4PU5BSH
EC Number
222-958-0
Nikkaji
J54.361F

物性

構造計算による物性

XLogP
0.1
極性表面積
42.5 Ų
水素結合供与体数
0
水素結合受容体数
2
回転可能結合数
1
重原子数
6

実験および物理化学的性質

SpringerMaterials PropertiesSchoenflies notation
Density1.2117 at 68 °F (NTP, 1992) - Denser than water; will sink
Solubility10 to 50 mg/mL at 63 °F (NTP, 1992)
Flash Pointgreater than 230 °F (NTP, 1992)
Boiling Point252 to 255 °F at 24 mmHg (NTP, 1992)
Physical DescriptionMethyl vinyl sulfone is a clear pale yellow liquid. (NTP, 1992)

物理化学的性質

沸点
115 · 115-117 °C19 mm Hg(lit.)
比重(密度)
1.212 g/mL · 1.212 g/mL at 25 °C(lit.)
屈折率
20 · n20/D 1.463(lit.)
闪点
230 °F · >230 °F
貯蔵温度
2 · 2-8°C
外見
液体

化学的性質

化学的特性light yellow liquid

安全と法規制

GHS分類

GHS Classification · 4 件

Danger

H302 (97.9%): Harmful if swallowed [Warning Acute toxicity, oral]

P262, P264, P264+P265, P270, P280, P301+P317, P302+P352, P305+P354+P338, P316, P317, P321, P330, P361+P364, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 48 reports by companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危険有害性情報

Regulatory InformationMethyl vinyl sulphone: HSNO Approval: HSR004560 Approved with controls
DOT LabelPoison
Fire HazardsThis chemical is probably combustible. (NTP, 1992)
Health HazardsSYMPTOMS: Exposure to this compound can result in irritation.
Reactive GroupHydrocarbons, Aliphatic Unsaturated
Reactivity AlertsPolymerizable

安全と保護具

Fire FightingFires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher. (NTP, 1992)
First Aid · 1 件

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Nonfire Spill Response · 1 件

SMALL SPILLS AND LEAKAGE: If you should spill this chemical, use absorbent paper to pick up all liquid spill material. Seal the absorbent paper, as well as any of your clothing which may be contaminated, in a vapor-tight plastic bag for eventual disposal. Wash any surfaces you may have contaminated with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

Isolation and EvacuationExcerpt from ERG Guide 153 [Substances - Toxic and/or Corrosive (Combustible)]:
Personal Protective Equipment (PPE)MINIMUM PROTECTIVE CLOTHING: If Tyvek-type disposable protective clothing is not worn during handling of this chemical, wear disposable Tyvek-type sleeves taped to your gloves.

安全データ

wgk
3
rtecs
WR6825000
ridadr
UN 2810 6.1/PG 1
hs_code
29309099
risk_code
22-27-41
消防法
危-4-3-III

化学と産業

応用分野 · 2 件

使用Methyl vinyl sulfone has been used:as derivatization reagent in an improved method for detection of pseudouridine in nucleoside mixtures by capillary HPLC-mass spectrometryin preparation of methylsulfonylethyl cellulose via Michael addition to cotton fabricin Heck vinylation of aryl halides

一般的な説明Clear pale yellow liquid.

調製方法

純化方法Pass the sulfone through a column of alumina, then de-gas, distil it in a vacuum line and store it at -190o until required. [Beilstein 1 III 1866.]

サプライヤー63 社

衢州润东化工有限公司0570-8789886 18892685668 · [email protected]
湖北万得化工有限公司15377098680 15377098680 · [email protected]
Hebei Chuanghai Biotechnology Co., Ltd+86-17732866630 · [email protected]
武汉欣扬瑞和化学科技有限公司153-07155313 15307155313 · [email protected]
Henan Rane Chemical Co., Ltd.+86-18738066252 · [email protected]

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