臭素酸

Bromic acid

HCID 24445CAS 7789-31-3

基本情報

標準SMILES
[O-][Br+2]([O-])O
InChIKey
YTFCQDDTLVUOCN-UHFFFAOYSA-N
分子式
BrHO3
平均分子量
128.91 g/mol
単同位体質量
127.91090599

概要

Bromic acid is a bromine oxoacid. It is a conjugate acid of a bromate.

名称と識別子

優先名称
Bromic acid
IUPAC
bromic acid
現地名
臭素酸
英語名
Bromic acid
分子式
BrHO3
分子量
128.91

名称と別名

Bromic acid7789-31-3908X3OZ87JDTXSID7064861CHEBI:49382HBrO3BromsaeurehydroxidodioxidobromineRefChem:121511(BrO2(OH))DTXCID9048065232-158-3
名称をさらに表示
臭素酸Bromhydric acid
Bromsaureacide bromiqueacido bromicoacidum bromicumUNII-908X3OZ87JEINECS 232-158-3BROMIC ACID [MI]BROMIC ACID (HBRO3)

データベース識別子

CAS
7789-31-3
PubChem CID
24445
DTXSID
DTXSID7064861
ChEMBL
CHEMBL1161635
ChEBI
CHEBI:49382
UNII
908X3OZ87J
EC Number
232-158-3
Nikkaji
J95.891C

物性

構造計算による物性

XLogP
-0.1
極性表面積
54.4 Ų
水素結合供与体数
1
水素結合受容体数
3
回転可能結合数
0
重原子数
4

実験および物理化学的性質

Chemical ClassesToxic Gases & Vapors -> Acids, Inorganic
Physical DescriptionFound only in aqueous solution: Colorless liquid; Turns yellow on standing; [Merck Index]

物理化学的性質

融点
100 ℃ · decomposes at 100℃ [CRC10]
比重(密度)
3.28 · 3.28 [HAW93]
溶解性
2 O · soluble in H2O
外見
水溶液中でのみ安定
色
stable only in aqueous solution
水溶解度
93 · aq メディアにのみ存在可能 [HAW93]

化学的性質

化学的特性colorless or slightly yellowish liquid; stable only in very dilute aqueous solutions; oxidizing agent; used in dyes [HAW93]

安全と法規制

危険有害性情報

Hazards SummaryA strong skin, eye, and mucous membrane irritant; [Merck Index] Unstable and exists only in dilute solutions; A strong tissue irritant; [Hawley] See Bromine.

毒性情報

Treatment · 1 件

EYES: irrigate opened eyes for several minutes under running water. INGESTION: do not induce vomiting. Rinse mouth with water (never give anything by mouth to an unconscious person). Seek immediate medical advice. SKIN: should be treated immediately by rinsing the affected parts in cold running water for at least 15 minutes, followed by thorough washing with soap and water. If necessary, the person should shower and change contaminated clothing and shoes, and then must seek medical attention. INHALATION: supply fresh air. If required provide artificial respiration.

Health Effects · 1 件

Bromine vapour causes irritation and direct damage to the mucous membranes. Elemental bromine also burns the skin. The bromide ion is a central nervous system depressant and chronic exposure produces neuronal effects. This is called bromism and can result in central reactions reaching from somnolence to coma, cachexia, exicosis, loss of reflexes or pathologic reflexes, clonic seizures, tremor, ataxia, loss of neural sensitivity, paresis, papillar edema of the eyes, abnormal speech, cerebral edema, delirium, aggressiveness, and psychoses. Bromate is also a potential carcinogen. (L625, L626, L627, L638)

Exposure RoutesOral (L96) ; inhalation (L96) ; dermal (L96)
Toxicity Summary · 1 件

Bromine is a powerful oxidizing agent and is able to release oxygen free radicals from the water in mucous membranes. These free radicals are also potent oxidizers and produce tissue damage. In additon, the formation of hydrobromic and bromic acids will result in secondary irritation. The bromide ion is also known to affect the central nervous system, causing bromism. This is believed to be a result of bromide ions substituting for chloride ions in the in actions of neurotransmitters and transport systems, thus affecting numerous synaptic processes. (L626, L627, A543)

Signs and Symptoms · 1 件

Bromine vapour causes irritation and direct damage to the mucous membranes. Symptoms include lacrimation, rhinorrhoea, eye irritation with mucous secretions from the oropharyngeal and upper airways, coughing, dyspnoea, choking, wheezing, epistaxis, and headache. The bromide ion is a central nervous system depressant producing ataxia, slurred speech, tremor, nausea, vomiting, lethargy, dizziness, visual disturbances, unsteadiness, headaches, impaired memory and concentration, disorientation and hallucinations. This is called bromism. (L626, L627)

Carcinogen ClassificationPotassium bromate: 2B, possibly carcinogenic to humans. (L135)

安全データ

tsca
TSCA listed
ridadr
3139
hazard_class
5.1
packing_group
II

化学と産業

薬理情報

Metabolism/Metabolites · 1 件

Bromine is mainly absorbed via inhalation, but may also enter the body through dermal contact. Bromine salts can be ingested. Due to its reactivity, bromine quickly forms bromide and may be deposited in the tissues, displacing other halogens. (L626)

用途と製造

UsesUsed as an oxidizing agent; [Merck Index] Used in dyes, intermediates, and pharmaceuticals; [Hawley]
General Manufacturing InformationBromic acid: INACTIVE

応用分野

使用Oxidizing agent.

使用用途臭素酸や臭素酸の塩は基本的に、酸化剤として使用されます。具体的には、合成原料、医薬品原料、染料の合成反応の中間処理剤として用いられる場合が多いです。 例えば、臭素酸カリウムは食品添加物 (小麦粉品質改良剤、魚肉製品添加剤) 、分析試薬に使用されます。また、臭素酸ナトリウムは医薬部外品添加物 (パーマネントウェーブ用剤) 、試薬などの用途があります。 ただし、臭素酸は強酸性、強酸化剤のため人体に有毒です。皮膚、眼、粘膜を侵すので、取り扱いに注意を要します。

調製方法 · 1 件

製造方法Bromic acid is prepared by adding sulfuric acid to barium bromate.Ba(BrO3)2 + H2SO4 → 2HBrO3 + BaSO4The product is distilled and absorbed in water. A 50% solution may be obtained by slow evaporation of the dilute solution in vacuum at -12°C.

サプライヤー6 社

上海参比医药科技有限公司(进口产品部)13368167990 · [email protected]
陕西缔都医药化工有限公司029-029-029-81148696 18161915376 · [email protected]
湖北玖天生物医药科技有限公司027-88013699 17354350817 · [email protected]
SUZHOU SENFEIDA CHEMICAL CO.,LTD+86-0512-83500002 +86-15195660023 · [email protected]
上海宝杨宝欣生物科技有限公司021-56698539 19921169802 · [email protected]

関連反応

24 件

関連ノート

読み込み中…