基本情報
- 標準SMILES
O.O.O.O.O.O.[Cl-].[Cl-].[Mg+2]- InChIKey
DHRRIBDTHFBPNG-UHFFFAOYSA-L- 分子式
- Cl2Mg.6H2O
- 平均分子量
- 203.3 g/mol
- 単同位体質量
- 201.98613516
概要
Magnesium dichloride hexahydrate is a hydrate that is the hexahydrate form of magnesium dichloride. It is a hydrate, an inorganic chloride and a magnesium halide. It contains a magnesium dichloride.
名称と識別子
- 優先名称
- Magnesium chloride hexahydrate
- IUPAC
- magnesium;dichloride;hexahydrate
- 現地名
- 化マグネシウム6水和物
- 英語名
- Magnesium chloride hexahydrate
- 分子式
- Cl2H12MgO6
- 分子量
- 203.3
名称と別名
名称をさらに表示
データベース識別子
- CAS
7791-18-6- PubChem CID
- 24644
- DTXSID
DTXSID0020789- ChEBI
CHEBI:86345- UNII
- 02F3473H9O
- EC Number
- 616-575-1
物性
構造計算による物性
- 極性表面積
- 6 Ų
- 水素結合供与体数
- 6
- 水素結合受容体数
- 8
- 回転可能結合数
- 0
- 重原子数
- 9
- 形式電荷
- 0
- 複雑度
- 0
実験および物理化学的性質
物理化学的性質
- 融点
- 117 °C · 117 °C
- 比重(密度)
- 1.569 · 1.569
- 貯蔵温度
- 2 · 2-8°C
- 溶解性
- 2 O: · H2O: 1M at20℃、透明、無色
- 外見
- 個体
- 色
- 白~ややグレー
- 比重
- 1.569 · 1.569
- 臭い (Odor)
- 無臭
- PH
- 4.5 · 4.5-7.0 (50g/l, H2O, 20℃)
- 水溶解度
- 2350 g/L · 2350g/L(20℃)
- Merck
- 14 · 14,5662
- 安定性
- 安定。強力な酸化剤とは相容れない。湿気から保護してください。
- 化粧品成分の機能
- 香料粘度制御
- InChI
- 1S/2ClH.Mg.6H2O/h2*1H;;6*1H2/q;;+2;;;;;;/p-2
- InChIKey
- DHRRIBDTHFBPNG-UHFFFAOYSA-L
- SMILES
- O.O.O.O.O.O.Cl[Mg]Cl
- LogP
- -1.38 · -1.380 (est)
- CAS データベース
- 7791 · 7791-18-6(CAS DataBase Reference)
- EPAの化学物質情報
- Magnesium chloride, hexahydrate (7791-18-6)
化学的性質
化学的特性The pure form of the compound is a colorless monoclinic crystal, but industrial versions typically have a yellowish-brown hue. It has a salty and bitter taste and is deliquescent. It is easily soluble in water and ethanol and will decompose when heated in air, releasing HCl gas around 118°C, which turns into oxychloride. When heated at high temperatures, it decomposes into MgO and HCl.
安全と法規制
GHS分類
GHS Classification
This chemical does not meet GHS hazard criteria for 97.1% (204 of 210) of all reports.
Not Classified
Aggregated GHS information provided per 210 reports by companies from 5 notifications to the ECHA C&L Inventory.
危険有害性情報
Regulatory Information
Chemical: Magnesium chloride, hexahydrate
Magnesium chloride hexahydrate: Does not have an individual approval but may be used under an appropriate group standard
安全と保護具
Protective Action Criteria (PAC)
24 [mg/m3]
270 [mg/m3]
1600 [mg/m3]
安全データ
- F
- 3
- wgk
- 1
- tsca
- Yes
- rtecs
- OM2975000
- 毒性
- LD50 orally in Rabbit: 8100 mg/kg
- hs_code
- 28273100
- risk_code
- 36/37/38
- hazard_code
- Xi
- safety_code
- 24/25-36-26
- ストレージクラス
- 13 - Non Combustible Solids
化学と産業
用途と製造
Uses
Used in wood fireproofing, wool carbonizing, and cotton fabric dressing; Also used in disinfectants, magnesia cements, fire extinguishers, floor sweeping compounds, and casein glue; Also used to make parchment paper and artificial leather; Has been used therapeutically as a cathartic and to treat bovine hypomagnesemia; [Merck Index] Used for dust suppression, deicing, and aqua-culture; [Great Salt Lake Minerals MSDS] Permitted for use as an inert ingredient in non-food pesticide products; [EPA]
Pulp and Paper Processing [Category: Industry]
Use Classification
EPA Safer Chemical Functional Use Classes -> Processing Aids and Additives
Safer Chemical Classes -> Green circle - The chemical has been verified to be of low concern
応用分野
用途汎用試薬。
用途高純度金属化合物。
用途酵素反応液活性化因子添加剤。PBSなどの塩溶液作製用。
用途試薬、豆腐製造、道路凍結防止剤等。
用途食品添加物。
用途マグネシアセメント原料、木材防腐、羊毛精製
説明Magnesium chloride hexahydrate is the hydrated form of magnesium chloride. Magnesium chloride is a mineral supplement used to prevent and treat low amounts of magnesium in the blood and a versatile compound with a number of uses in food preparation, health and personal well-being areas. Magnesium chloride is also used in road care, to synthesize other magnesium compounds, to remove dyes and industrial dye wastes, for the dust control, in the textile production, and as an industrial dye and dye waste remover. Magnesium chloride hexahydrate is used as catalyst for organic synthesis, e.g. 3,4‐Dihydropyrimidin‐2‐(1H)‐one. Magnesium chloride hexahydrate is also a promising heat/thermal storage material.
使用Magnesium chloride hexahydrate has been used in wash buffer for the purification of protein from Saccharomyces cerevisiae.It has been used for the preparation of extracellular (Ringer) solution for juxtacellular recording of single neurons in freely moving rats.It has been used as a supplement to study effect of desiccation on bacterial viability.
一般的な説明Magnesium chloride hexahydrate is a colorless, crystalline solid. On heating, it loses water of crystallization and affords magnesium oxide. It has been tested as a potential phase change material (PCM) for use in cooking indoors and during the low intensity solar radiation periods. Due to its suitable thermo-physical properties, it can be used as storage media in solar cookers. Its flame retardancy action on 100% woven cotton fabric has been investigated. Its heat capacity has been evaluated.
調製方法
純化方法Crystallise it from hot water (3.3g/mL) by cooling. Dry it in a vacuum at ~175o, or heat the hydrate in a stream of HCl. When the hydrate is heated above 180o it is hydrolysed to the oxychloride (Mg2OCl2). It is deliquescent; store it in a well-stoppered vessel. [Bryce-Smith Inorg Synth VI 9 1960, Ehrlich in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I p 908 1963.]
上流・下流製品情報
上流原料
下流製品
サプライヤー50 社
補足説明
定義本品は、マグネシウムの塩化物であり、次の化学式で表される。
定義ChEBI: Magnesium dichloride hexahydrate is a hydrate that is the hexahydrate form of magnesium dichloride. It is a hydrate, a magnesium halide and an inorganic chloride. It contains a magnesium dichloride.
関連反応
関連ノート
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