CAS 38274-14-5 2,2'-Bis(bromomethyl)-1,1'-biphenyl (HCID 251962)

基本情報

CAS: 38274-14-5
標準SMILES: BrCc1ccccc1-c1ccccc1CBr
InChIKey: VDXGURZGBXUKES-UHFFFAOYSA-N
分子式: C14H12Br2
平均分子量: 340.05 g/mol
単同位体質量: 337.93057458

名称と識別子

優先名称: 2,2'-Bis(bromomethyl)-1,1'-biphenyl
IUPAC: 1-(bromomethyl)-2-[2-(bromomethyl)phenyl]benzene
現地名: 2,2′-ビス(ブロモメチル)-1,1′-ビフェニル
英語名: 2,2'-BIS(BROMOMETHYL)-1,1'-BIPHENYL
分子式: C14H12Br2
分子量: 340.05

名称と別名

2,2'-Bis(bromomethyl)-1,1'-biphenylRefChem:440239628-317-538274-14-52,2'-Bis(bromomethyl)biphenyl1-(bromomethyl)-2-[2-(bromomethyl)phenyl]benzene2,2'-Bis-bromomethyl-biphenyl2,2'-dibromomethyl-1,1'-biphenylMFCD000749102,2'-dibromomethylbiphenylo,o'-Bitolyl, a,a'-dibromo-DTXSID90291081

名称をさらに表示

2,2′-ビス(ブロモメチル)-1,1′-ビフェニル-Bis(bromomethyl)-1,1′2,2'-Bisbromomethyl-biphenyl2,2'-bis(bromethyl)-1,1'-biphenyl2,2'-Bis(broMoMethyl)-1,1'-biphenyl 99%2,2′-Bis(bromomethyl)-1,1′-biphenyl, CAS 38274-14-5

2,2 inverted exclamation marka-Bis(bromomethyl)-1,1 inverted exclamation marka-biphenyl1,1'-Biphenyl, 2,2'-bis(bromomethyl)-2,2'-Bis(bromomethyl)-1,1'-biphenyl, 99%NSC73047FT-0746744NCIOpen2_008806o,o'-Bis(bromomethyl)biphenyl2,2'-di(brommethyl)-diphenyl

データベース識別子

CAS: 38274-14-5
PubChem CID: 251962
DTXSID: DTXSID90291081
EC Number: 628-317-5
Nikkaji: J725.711B

物性

構造計算による物性

XLogP: 4.7
極性表面積: 0 Å²
水素結合供与体数: 0
水素結合受容体数: 0
回転可能結合数: 3
重原子数: 16
形式電荷: 0
複雑度: 183

実験および物理化学的性質

SpringerMaterials PropertiesChemical shift

物理化学的性質

融点: 90 · 90-92 °C(lit.)
沸点: 148 · 148-150 °C(Press: 0.002 Torr)
比重(密度): 1.591 · 1.591±0.06 g/cm3(Predicted)
貯蔵温度: 2 · Storage temp. 2-8°C
外見: powder
色: White
InChI: 1S/C14H12Br2/c15-9-11-5-1-3-7-13(11)14-8-4-2-6-12(14)10-16/h1-8H,9-10H2
InChIKey: VDXGURZGBXUKES-UHFFFAOYSA-N
SMILES: BrCc1ccccc1-c2ccccc2CBr

安全と法規制

GHS分類

GHS Classification · 4 件

Danger

H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]

P260, P261, P264, P264+P265, P271, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P351+P338, P305+P354+P338, P316, P319, P321, P337+P317, P363, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 39 reports by companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危険有害性情報

Hazard Classes and CategoriesSkin Corr. 1B (100%)

安全データ

wgk: 3
ridadr: UN 3261 8/PG 2
hs_code: 2902900000
risk_code: 34-36/37
hazard_code: C
safety_code: 26-27-28-36/37/39-45
hazard_class: 8
packing_group: III
Hazard Classifications: Eye Irrit. 2Skin Corr. 1BSTOT SE 3
ストレージクラス: 8A - Combustible corrosive hazardous materials

化学と産業

応用分野 · 1 件

使用2,2′-Bis(bromomethyl)-1,1′-biphenyl was used in the preparation of mononuclear rhodium(III) complex with a nine-membered S, S-chelate ring. It was also used in the preparation of 1,1′-binaphthyl-substituted α-aminoisobutyric acid, a new chiral atropoisomeric α,α-disubstituted glycine.