ジアミノマレオニトリル

Diaminomaleonitrile

HCID 2723951

基本情報

CAS
1187-42-4
標準SMILES
N#C/C(N)=C(/N)C#N
InChIKey
DPZSNGJNFHWQDC-ARJAWSKDSA-N
分子式
C4H4N4
平均分子量
108.1 g/mol
単同位体質量
108.04359613

概要

Diaminomaleonitrile is a brown powder. (NTP, 1992)

名称と識別子

優先名称
Diaminomaleonitrile
IUPAC
(Z)-2,3-diaminobut-2-enedinitrile
現地名
ジアミノマレオニトリル
英語名
Diaminomaleonitrile
分子式
C4H4N4
分子量
108.1

名称と別名

DIAMINOMALEONITRILE1187-42-42,3-DiaminomaleonitrileHydrogen cyanide tetramerMaleonitrile, diamino-2-Butenedinitrile, 2,3-diamino-, (2Z)-2-Butenedinitrile, 2,3-diamino-, (Z)-1,2-Diamino-1,2-dicyanoethyleneE8C63N8TWRNSC-2667582,3-Diamino-2-butenedinitrile18514-52-8
名称をさらに表示
ジアミノマレオニトリル2,3-ジアミノマレオニトリルシアン化水素四量体(Z)-2,3-ジアミノ-2-ブテンジニトリル1,2-ジアミノ-1,2-ジシアノエチレンeonitriLDiaminomaL2,3-DiaminoTIMTEC-BB SBB009976Diaminomalononitrilediaminoaleo dinitrileDiaminomaleonitrile 98%Diaminomaleonitrile,98%
RefChem:586213214-697-6DAMN(Z)-2,3-diaminobut-2-enedinitrile(2Z)-diaminobut-2-enedinitrileDTXSID0024923(2Z)-2,3-diaminobut-2-enedinitrile(2Z)-2,3-Diamino-2-butenedinitrile

データベース識別子

CAS
1187-42-4、18514-52-8
PubChem CID
2723951
DTXSID
DTXSID0024923
ChEMBL
CHEMBL1701646
UNII
E8C63N8TWR
EC Number
214-697-6
Nikkaji
J38.151I

物性

構造計算による物性

XLogP
-1
極性表面積
99.6 Ų
水素結合供与体数
2
水素結合受容体数
4
回転可能結合数
0
重原子数
8

実験および物理化学的性質

SpringerMaterials PropertiesCrystal structure
Solubilityless than 1 mg/mL at 63 °F (NTP, 1992)
Melting Point352 to 365 °F (NTP, 1992)
Physical DescriptionDiaminomaleonitrile is a brown powder. (NTP, 1992)

物理化学的性質

融点
178 · 178-179 °C (lit.)
沸点
192.71 °C · 192.71°C (rough estimate)
比重(密度)
1 · 1,36 g/cm3
屈折率
1.626 · 1.6260 (estimate)
貯蔵温度
Keep in dark place,Sealed in dry,Room Temperature
溶解性
5000 mg/l · 5000mg/l

化学的性質

化学的特性brown crystalline powder

安全と法規制

GHS分類

GHS Classification · 4 件

Danger

H301 (27.6%): Toxic if swallowed [Danger Acute toxicity, oral]

P261, P264, P270, P271, P280, P301+P316, P301+P317, P302+P352, P304+P340, P317, P321, P330, P362+P364, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 58 reports by companies from 9 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危険有害性情報

Regulatory InformationDiaminomaleonitrile: Does not have an individual approval but may be used under an appropriate group standard
DOT LabelPoison
Fire HazardsFlash point data are not available for this compound, but it is probably combustible. (NTP, 1992)
Health HazardsExcerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:
Reactive GroupAmines, Phosphines, and Pyridines
Reactivity ProfileDIAMINOMALEONITRILE is sensitive to prolonged exposure to air. (NTP, 1992)

安全と保護具

Fire FightingFires involving this compound should be controlled using a dry chemical, carbon dioxide or Halon extinguisher. (NTP, 1992)
First Aid · 1 件

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Nonfire Spill Response · 1 件

SMALL SPILLS AND LEAKAGE: Should a spill occur while you are handling this chemical, you should dampen the solid spill material with alcohol, then transfer the dampened material to a suitable container. Use absorbent paper dampened with alcohol to pick up any remaining material. Seal the absorbent paper, and any of your clothes, which may be contaminated, in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with alcohol followed by washing with a strong soap and water solution. Do not reenter the contaminate area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

Isolation and EvacuationExcerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:
Personal Protective Equipment (PPE) · 1 件

RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with a combination filter cartridge, i.e. organic vapor/acid gas/HEPA (specific for organic vapors, HCl, acid gas, SO2 and a high efficiency particulate filter). (NTP, 1992)

安全データ

wgk
3
tsca
TSCA listed
ridadr
UN 3439 6.1/PG 3
hs_code
29269095
risk_code
20/21/22-25
化審法
(2)-1525

化学と産業

用途と製造

General Manufacturing Information2-Butenedinitrile, 2,3-diamino-, (2Z)-: ACTIVE

応用分野

用途有機合成原料。

一般的な説明Brown powder.

調製方法

製造方法Diaminomaleonitrile is obtained by tetramerization of hydrocyanic acid in the presence of catalysts such as alkylaluminum compounds.

サプライヤー100 社

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関連反応

53 件

化合物ノート

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