O-(トリメチルシリル)ヒドロキシルアミン

O-(Trimethylsilyl)hydroxylamine

HCID 2734666

ノート反応

部分構造検索類似構造を探す

基本情報

CAS: 22737-36-6
標準SMILES: C[Si](C)(C)ON
InChIKey: AEKHNNJSMVVESS-UHFFFAOYSA-N
分子式: C3H11NOSi
平均分子量: 105.21 g/mol
単同位体質量: 105.0609905

名称と識別子

優先名称: O-(Trimethylsilyl)hydroxylamine
IUPAC: O-trimethylsilylhydroxylamine
現地名: O-(トリメチルシリル)ヒドロキシルアミン
英語名: O-(TRIMETHYLSILYL)HYDROXYLAMINE
分子式: C3H11NOSi
分子量: 105.21

名称と別名

O-(Trimethylsilyl)hydroxylamine22737-36-6DTXSID40370436RefChem:167113DTXCID70321471626-309-6O-trimethylsilylhydroxylamineMFCD00010872AminoxytrimethylsilaneTMSONH2O-trimethylsilyl-hydroxylamineO-(Trimethylsilylhydroxyl)amine

名称をさらに表示

O-(トリメチルシリル)ヒドロキシルアミン97% Min.AKOS MSC-0140(Aminooxy)trimethylsilane0-TrimethylsilylhydroxylamineO-(Trimethylsilyl)hydroxylamine,97%O-(TRIMETHYLSILYL)HYDROXYLAMINE,PRACTO-TriMethylsilyl hydroxylaMine Min 97%

Hydroxylamine, O-(trimethylsilyl)-C3H11NOSiO-TMS-hydroxylamineMe3SiONH2SCHEMBL5769O-trimethylsilyl hydroxylamineO-Trimethylsilyl)hydroxylamineSCHEMBL2765497

データベース識別子

CAS: 22737-36-6
PubChem CID: 2734666
DTXSID: DTXSID40370436
EC Number: 626-309-6
Nikkaji: J1.838.385C

物性

構造計算による物性

極性表面積: 35.3 Å²
水素結合供与体数: 1
水素結合受容体数: 2
回転可能結合数: 1
重原子数: 6
形式電荷: 0
複雑度: 40.5

実験および物理化学的性質

SpringerMaterials Properties29Si nuclear magnetic resonance spectrum

物理化学的性質

沸点: 98 · 98-100 °C(lit.)
比重(密度): 0.86 g/mL · 0.86 g/mL at 25 °C(lit.)
屈折率: 20 · n20/D 1.405(lit.)
闪点: 48 °F · 48 °F
貯蔵温度: 2 · 2-8°C
外見: 液体
酸解離定数(Pka): 3.28 · 3.28±0.70(Predicted)
比重: 0.86 · 0.860
色: 無色透明
BRN: 2035893 · 2035893
InChI: 1S/C3H11NOSi/c1-6(2,3)5-4/h4H2,1-3H3
InChIKey: AEKHNNJSMVVESS-UHFFFAOYSA-N
SMILES: C[Si](C)(C)ON
CAS データベース: 22737 · 22737-36-6(CAS DataBase Reference)

化学的性質

化学的特性clear colorless liquid

安全と法規制

GHS分類

GHS Classification · 4 件

Danger

H225 (100%): Highly Flammable liquid and vapor [Danger Flammable liquids]

P210, P233, P240, P241, P242, P243, P260, P264, P280, P301+P330+P331, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P321, P363, P370+P378, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 42 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危険有害性情報

Hazard Classes and CategoriesFlam. Liq. 2 (100%)

安全データ

F: 10-21
wgk: 3
tsca: No
ridadr: UN 2733 3/PG 2
hs_code: 29310099
risk_code: 11-34
消防法: 危-4-1-II
hazard_code: F,C
safety_code: 16-26-36/37/39-45
hazard_class: 3.1
packing_group: II
Hazard Classifications: Flam. Liq. 2Skin Corr. 1B
ストレージクラス: 3 - Flammable liquids

化学と産業

応用分野

使用O-(Trimethylsilyl)hydroxylamine may be used for the preparation of O-trimethylsilyl oxime ethers.

一般的な説明O-(Trimethylsilyl)hydroxylamine is an O-substituted hydroxylamine. It is formed as an intermediate during the trimethylsilyl chloride catalyzed synthesis of α-branched amines.