1-ヨードプロパン
1-Iodopropane
基本情報
- CAS
107-08-4- 標準SMILES
CCCI- InChIKey
PVWOIHVRPOBWPI-UHFFFAOYSA-N- 分子式
- C3H7I
- 平均分子量
- 169.99 g/mol
- 単同位体質量
- 169.95925
概要
Iodopropanes appears as a colorless liquid that discolors in air. Denser than water. The vapors are heavier than air. May be mildly toxic by inhalation. Used as a solvent and to make pharmaceuticals.
名称と識別子
- 優先名称
- 1-Iodopropane
- IUPAC
- 1-iodopropane
- 現地名
- 1-ヨードプロパン
- 英語名
- 1-Iodopropane
- 分子式
- C3H7I
- 分子量
- 169.99
名称と別名
1-IODOPROPANE107-08-4Propyl iodidePropane, 1-iodo-ND3629KE2KDTXSID501015653RefChem:869737DTXCID3037595203-460-2n-Propyl iodidePropane, iodo-IODOPROPANE
名称をさらに表示
1-ヨードプロパンよう化プロピルプロピルヨージドn-プロピルヨージドよう化n-プロピルヨウ化-n-プロピル1-ヨードプロパン ヨウ化プロピル ヨウ化物1‐ヨードプロパンn-C3H7IPropyljodid1-Iodpropanen-Propyliodid1-iodo-propanproopyl iodide
1-iodo-propane1-Jodpropaniodopropanl-iodopropane26914-02-3l-propyl iodideMFCD00001095PROPYLIODIDE
データベース識別子
- CAS
107-08-4、26914-02-3- PubChem CID
- 33643
- DTXSID
DTXSID501015653- UNII
- ND3629KE2K
- EC Number
- 203-460-2
- Nikkaji
- J4.051G
物性
構造計算による物性
- XLogP
- 2.6
- 極性表面積
- 0 Ų
- 水素結合供与体数
- 0
- 水素結合受容体数
- 0
- 回転可能結合数
- 1
- 重原子数
- 4
- 形式電荷
- 0
- 複雑度
- 7.2
実験および物理化学的性質
Chemical Classes
Other Classes -> Halogenated Aliphatics, Saturated
Flammable agents - 2nd degree
SpringerMaterials PropertiesCoriolis coupling
LogP2.54
Vapor Pressure43.1 [mmHg]
Physical Description
Iodopropanes appears as a colorless liquid that discolors in air. Denser than water. The vapors are heavier than air. May be mildly toxic by inhalation. Used as a solvent and to make pharmaceuticals.
Colorless or yellowish liquid; [Merck Index]
物理化学的性質
- 融点
- -101 °C · -101 °C
- 沸点
- 101 · 101-102 °C(lit.)
- 比重(密度)
- 1.743 g/mL · 1.743 g/mL at 25 °C(lit.)
- 蒸気圧
- 43 mm · 43 mm Hg ( 25 °C)
- 屈折率
- 20 · n20/D 1.504(lit.)
- 闪点
- 112 °F · 112 °F
- 貯蔵温度
- 30 °C · Store below +30°C.
- 溶解性
- 1.1 g/リットル · 1.1g/リットル
安全と法規制
安全情報は参考情報です。供給元の安全データシート（SDS）、適用法令、専門家による評価に代わるものではありません。
GHS分類
GHS Classification
Warning
H226 (100%): Flammable liquid and vapor [Warning Flammable liquids]
P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P270, P271, P273, P280, P301+P317, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P317, P319, P321, P330, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 50 reports by companies from 9 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
危険有害性情報
Regulatory Information
Chemical: Propane, 1-iodo-
REACH registered substance: 1-iodopropane (EC: 203-460-2)
1-Iodopropane: Does not have an individual approval but may be used under an appropriate group standard
The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)
DOT LabelFlammable Liquid
Fire HazardsExcerpt from ERG Guide 129 [Flammable Liquids (Water-Miscible / Noxious)]:
Health HazardsExcerpt from ERG Guide 129 [Flammable Liquids (Water-Miscible / Noxious)]:
Hazards SummaryAn irritant; Harmful by inhalation; [Alfa Aesar MSDS]
Reactive GroupHalogenated Organic Compounds
Reactivity AlertsHighly Flammable
Reactivity Profile
化学と産業
薬理情報
Metabolism/Metabolites1-iodopropane has known human metabolites that include propyl-glutathione.
用途と製造
General Manufacturing InformationPropane, 1-iodo-: ACTIVE
応用分野
用途プロピル化剤や医薬品，工業用原料
使用1-Iodopropane is used in wide range of medicals industrial applications as well as in human and animal nutrition products, pharmaceutical intermediates, polarizing films for Liquid Crystal Display (LCD) chemicals. Iodine derivatives are also used as organic building blocks, analytical reagents etc. It is also used as a solvent and intermediate of organic synthesis.
調製方法
合成方法乾燥した1-プロパノールにヨウ素とリンを作用させて製造される
純化方法It should be distilled first under reduced pressure to avoid decomposition. Dry the iodide with MgSO4 or silica gel and fractionally distil it. Store it under nitrogen with mercury in a brown bottle. Prior to distillation, free iodine can be removed by shaking with copper powder or by washing with aqueous Na2S2O3 and drying. Alternatively, the n-propyl iodide can be treated with bromine, then washed with aqueous Na2S2O3, dried and distilled. See also n-butyl iodide. [Beilstein 1 IV 222.]
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