硫酸水素ナトリウム

Bisulfate, aqueous solution is a white crystalline solid dissolved in water. It is corrosive to metals and tissue.

Other Solid; Dry Powder; Liquid; Other Solid; Liquid

White, odourless crystals or granules

White crystals dissolved in water; [CAMEO] Hygroscopic crystals; [CHEMINFO]

Danger

H318: Causes serious eye damage [Danger Serious eye damage/eye irritation]

P264+P265, P280, P305+P354+P338, and P317 (click each P-code to see the statement)

This chemical does not meet GHS hazard criteria for 0.3% (2 of 794) of reports.

Danger

H318 (99.6%): Causes serious eye damage [Danger Serious eye damage/eye irritation]

Chemical: Sulfuric acid, monosodium salt

Regulation (EC) No 1333/2008 (amended)

Sulfuric acid, sodium salt (1:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Sulfuric acid, sodium salt (1:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 24-02-2020 https://echa.europa.eu/registration-dossier/-/registered-dossier/14458

Sodium hydrogen sulphate: Does not have an individual approval but may be used under an appropriate group standard

Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:

· Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.

Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:

· TOXIC and/or CORROSIVE; inhalation, ingestion or skin contact with material may cause severe injury or death.

Corrosive to metals and tissues; Toxic by ingestion, inhalation, or skin contact; [CAMEO] Aqueous solutions are strong acids; [Merck Index] Harmful if swallowed; Do not inhale dust or aerosol; may cause acute lung edema if inhaled; [MSDSonline] Based on animal studies, not a skin irritant; [CHEMINFO]

Acidic salts, such as SODIUM BISULFATE, SOLUTION, are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pHs of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions. The combination of calcium hypochlorite, sodium hydrogen sulfate, starch, and sodium carbonate, when compressed, caused the materials to incandescence, followed by explosion, [Ind. Eng. Chem., 1937, 15, 282].

Eye Dam. 1 (99.6%)

Eye damage - category 1

Serious eye damage/eye irritation - Category 2

Eye Dam. 1

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.

Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:

General First Aid:

Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:

Immediate precautionary measure

8.4 [mg/m3]

92 [mg/m3]

550 [mg/m3]

Used as a bactericide and disinfectant; [ChemIDplus] Used to pickle metals, carbonize wool, bleach leather, and manufacture magnesia cements; [Merck Index]

Acid and Alkali Cleaning of Metals [Category: Clean]

EPA Safer Chemical Functional Use Classes -> Antimicrobial Actives;Processing Aids and Additives

Safer Chemical Classes -> Green circle - The chemical has been verified to be of low concern

Food additives

Food Additives -> ACID -> JECFA Functional Classes

Cosmetics -> Buffering

Miscellaneous Manufacturing

Sulfuric acid, sodium salt (1:1): ACTIVE