クロロジイソプロピルホスフィン

Chlorodiisopropylphosphine

HCID 538967

基本情報

CAS
40244-90-4
標準SMILES
CC(C)P(Cl)C(C)C
InChIKey
JZPDBTOWHLZQFC-UHFFFAOYSA-N
分子式
C6H14ClP
平均分子量
152.6 g/mol
単同位体質量
152.0521651

名称と識別子

優先名称
Chlorodiisopropylphosphine
IUPAC
chloro-di(propan-2-yl)phosphane
現地名
クロロジイソプロピルホスフィン
英語名
Chlorodiisopropylphosphine
分子式
C6H14ClP
分子量
152.6

名称と別名

Chlorodiisopropylphosphine40244-90-45FG5N54CYBDTXSID10337132RefChem:575823DTXCID00288220629-426-0DiisopropylchlorophosphinePhosphinous chloride, bis(1-methylethyl)-chloro-di(propan-2-yl)phosphaneChlorobis(isopropyl)phosphineiPr2PCl
名称をさらに表示
クロロジイソプロピルホスフィンジイソプロピル亜ホスフィン酸クロリドジイソプロピルクロロホスフィンクロロビス(1-メチルエチル)ホスフィンジ-i-プロピルクロロホスフィン, min. 97%クロロビス(プロパン-2-イル)ホスファンDi-i-propyLAURORA KA-131898% (i-Pr)2PClCHLORODIISOPROPYLPHOSHINEbis-isopropylchlorophosphineCHLORODIISOPROPYLPHOSPHINE,96%
MFCD00015027ChlorodiiosopropylphosphineUNII-5FG5N54CYBP,P-Bis(1-methylethyl)phosphinous chloridePhosphinous chloride, P,P-bis(1-methylethyl)-Di-i-propylchlorophosphinedi-isopropylchlorophosphineC6H14ClP

データベース識別子

CAS
40244-90-4
PubChem CID
538967
DTXSID
DTXSID10337132
UNII
5FG5N54CYB
EC Number
629-426-0
Nikkaji
J121.063G

物性

構造計算による物性

XLogP
2.3
極性表面積
0 Ų
水素結合供与体数
0
水素結合受容体数
0
回転可能結合数
2
重原子数
8

物理化学的性質

沸点
69 °C33 · 69 °C33 mm Hg(lit.)
比重(密度)
0.959 g/mL · 0.959 g/mL at 25 °C(lit.)
屈折率
20 · n20/D 1.475(lit.)
闪点
39 °F · 39 °F
貯蔵温度
Refrigerator
外見
液体

化学的性質

化学的特性Colorless to light yellow liqui

安全と法規制

GHS分類

GHS Classification · 5 件

Danger

H225 (100%): Highly Flammable liquid and vapor [Danger Flammable liquids];H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]

P210, P233, P240, P241, P242, P243, P260, P264, P280, P301+P330+P331, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P321, P363, P370+P378, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 42 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.;Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

危険有害性情報

Hazard Classes and CategoriesFlam. Liq. 2 (100%);Skin Corr. 1B (100%)

安全データ

wgk
3
ridadr
UN 2924 3/PG 2
hs_code
29310099
risk_code
11-34
消防法
危-4-1-II
hazard_code
F,C

化学と産業

応用分野 · 2 件

説明Chlorodiisopropylphosphine is an organophosphorus compound of particular interest in synthetic chemistry, where it is used as a reagent in the preparation of phosphine ligands for transition metal complexes. Its utility in synthesising these complexes is due to the reactivity of the chloro group, which other groups can substitute to create a diverse array of ligands. This reactivity is also exploited in the study of catalysis, as the resulting phosphine ligands can be used to modulate the activity and selectivity of metal catalysts. In addition, Chlorodiisopropylphosphine is investigated for its potential in forming new organophosphorus compounds with applications in materials science. Researchers are also interested in the compound′s role in synthesising flame retardants, where its phosphorus content could contribute to the material′s flame-retarding properties.

使用Chlorodiisopropylphosphine can be used: To synthesize p-styryldiisopropylphosphine by reacting with 4-chlorostyrene via Grignard reaction.As a phosphination reagent in combination with [Cp2Zr(1-butene)(DMAP)] (Cp=cyclopentadienyl; DMAP= 4-(dimethylamino)pyridine)) for the zirconophosphination of alkynes to form zirconoalkenylphosphines.A luminescent mixed-donor platinum POCN pincer complex via cyclometalation process.

調製方法

合成方法PCl3のエーテル溶液にイソプロピルマグネシウムクロリドを加える。

サプライヤー100 社

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
阿诺西(上海)生物技术有限公司400-1107768 15058188853 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
杭州鸿喜生物医药科技有限公司18989489206 · [email protected]
武汉欣扬瑞和化学科技有限公司13720274133 · [email protected]

関連反応

26 件

化合物ノート

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