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りん酸三ナトリウム·12水和物

Trisodium phosphate dodecahydrate

HCID 61473
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基本情報名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
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基本情報

CAS
10101-89-0
標準SMILES
O.O.O.O.O.O.O.O.O.O.O.O.O=P([O-])([O-])[O-].[Na+].[Na+].[Na+]
InChIKey
ASTWEMOBIXQPPV-UHFFFAOYSA-K
分子式
H24Na3O16P
平均分子量
380.12 g/mol
単同位体質量
380.04950452

名称と識別子

優先名称
Trisodium phosphate dodecahydrate
IUPAC
trisodium;phosphate;dodecahydrate
現地名
りん酸三ナトリウム·12水和物
英語名
Sodium phosphate tribasic dodecahydrate
分子式
H6NaO5P
分子量
140.01

名称と別名

Trisodium phosphate dodecahydrate10101-89-0Sodium phosphate tribasic dodecahydrateSodium phosphate dodecahydratePhosphoric acid, trisodium salt, dodecahydratesodium phosphate, tribasic, dodecahydratePhosphoric acid, trisodium salt, dodeahydrateB70850QPHRFRESH AQUAVEGE AQUADTXSID0049810RefChem:56038
名称をさらに表示
オルトりん酸三ナトリウム12水和物りん酸ナトリウム·10水和物りん酸三ナトリウム·12水和物りん酸ナトリウム10水和物リン酸三ナトリウム(水)第三燐酸ソーダ·12水塩りん酸ナトリウム,第三 12水りん酸三ナトリウム?12水りん酸三ナトリウム12水りん酸三ナトリウム?12水和物三塩基性リン酸ナトリウム十二水和物 ACS REAGENT,≥98%三塩基性リン酸ナトリウム十二水和物 PURISS. P.A.,ACS REAGENT,≥98.0% (T)りん酸ナトリウム三塩基性十二水和物りん酸ナトリウム十二水和物りん酸三ナトリウム・12水三塩基性リン酸ナトリウム 十二水和物りん酸三ナトリウム1 2 水りん酸ナトリウム十二水和物, 97%りん酸ナトリウム十二水和物, 98+% (ACS)りん酸三ナトリウム・12水和物TSPSODIUM PHOSPHATE TRIBASICTRI-SODIUM PHOSPHATE DODECAHYDRATEsodiuM phosphatTRI-SODIUM ORTHOPHOSPHATE DODECAHYDRATEKH2PO9TSP, 12-HYDRATETSP dodecahydrateTRISODIUM PHOSHATE

データベース識別子

CAS
10101-89-0
PubChem CID
61473
DTXSID
DTXSID0049810
UNII
B70850QPHR
EC Number
600-151-8

物性

構造計算による物性

極性表面積
98.3 Ų
水素結合供与体数
12
水素結合受容体数
16
回転可能結合数
0
重原子数
20
形式電荷
0
複雑度
36.8

実験および物理化学的性質

Chemical ClassesOther Classes -> Salts, Basic
Melting PointMelting point equals 164 to 170 ° F
Physical Description · 2 件

Liquid; Dry Powder

Colorless to white crystals; [CAMEO]

物理化学的性質

融点
75 °C · 75 °C
比重(密度)
1.62 g/mL · 1.62 g/mL at 25 °C
貯蔵温度
5 °C · Store at +5°C to +30°C.
溶解性
2 O: · H2O: 0.5M at20℃、透明、無色
外見
個体
比重
1.62 · 1.62
色
白い
PH
12 · 12 (10g/l, H2O, 20℃)
水溶解度
258 g/L · 258g/L(20℃)
Merck
14 · 14,8662
安定性
安定。強酸とは相容れない。乾いた状態に保ちます。
InChI
1S/3Na.H3O4P.12H2O/c;;;1-5(2,3)4;;;;;;;;;;;;/h;;;(H3,1,2,3,4);12*1H2/q3*+1;;;;;;;;;;;;;/p-3
InChIKey
ASTWEMOBIXQPPV-UHFFFAOYSA-K
SMILES

安全と法規制

安全情報は参考情報です。供給元の安全データシート(SDS)、適用法令、専門家による評価に代わるものではありません。

GHS分類

GHS Classification · 6 件

This chemical does not meet GHS hazard criteria for 1.3% (6 of 472) of reports.

Danger

H314 (20.8%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]

P260, P261, P264, P264+P265, P271, P280, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P351+P338, P305+P354+P338, P316, P319, P321, P332+P317, P337+P317, P362+P364, P363, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 472 reports by companies from 17 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

危険有害性情報

Regulatory Information · 3 件

Chemical: Phosphoric acid, trisodium salt, dodecahydrate

Phosphoric acid, trisodium salt, dodecahydrate is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Phosphoric acid, trisodium salt, dodecahydrate are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Trisodium phosphate: Does not have an individual approval but may be used under an appropriate group standard

Other Safety InformationIMAP assessments - Trisodium phosphate: Human health tier II assessment
Hazards SummaryCan cause burns to the eyes and skin; Harmful if ingested; [CAMEO] Aqueous solutions are highly alkaline; [HSDB] Dusts and solutions > 0.1% are corrosive to the eyes and possibly to the skin; [CHEMINFO]
Hazard Classes and Categories · 2 件

Skin Corr. 1C (20.8%)

Skin corrosion - category 1B

毒性情報

化学と産業

用途と製造

Uses · 2 件

Used to develop photos, clarify sugar, remove boiler scale, soften water, manufacture paper, tan leather, and make detergents; [HSDB] Used in food to increase alkalinity; [CHEMINFO]

Pulp and Paper Processing [Category: Industry]

U.S. Production2023: 1,112,954 lb
Consumer UsesNot Known or Reasonably Ascertainable
Industry UsesCleaning agent
General Manufacturing InformationSoap, Cleaning Compound, and Toilet Preparation Manufacturing
応用分野 · 4 件

用途清缶剤、染色助剤

説明Sodium phosphate tribasic dodecahydrate is also known as trisodium phospate or TSP. It is a highly soluble in water and widely used as a cleaning agent. The pH of a 1% solution is typically around 12, making this reagent sufficiently alkaline for saponification of grease and oils. In combination with surfactants, TSP is an excellent agent for cleaning everything from laundry to concrete driveways. This versatility and low manufacturing price made TSP the basis for a plethora of cleaning products sold in the mid-20th century. Trisodium phosphate is used in the isolation of mycobacteria, including culturing of tubercle bacilli. Has been used as a protein precipitant in certain applications and in co-precipitation and fractionization of nucleotides. May be used for the preservation of biologically active soil samples. Because of the alkaline pH, TSP disrupts cytoplasmic and outer membranes of Salmonella enterica cells making it useful in preventing the spread of bacteria. It is used in photographic developing, clarifying sugar, removing boiler scale, softening water and manufacturing of paper. They are added to many foods as an emulsifier to prevent oil separation. It can be utilized as a leavening agent. Some instances of these foods include the batter coating on breaded fish or chicken, and commercially baked cakes. Adding this item to food increases the shelf life of the food, maintaining the texture and visual aspect of the food.

関連反応

7 件
反応記録を作成
HRID 413620 の反応式
HRID 413620反応物としてuspto-grants-2003_05
HRID 435512 の反応式
HRID 435512反応物としてuspto-grants-1983_08
HRID 1282019 の反応式
HRID 1282019反応物としてuspto-grants-2002_09
HRID 1510813 の反応式
HRID 1510813反応物としてuspto-grants-2012_07
HRID 1510815 の反応式
HRID 1510815反応物としてuspto-grants-2012_07
HRID 1633392 の反応式
HRID 1633392反応物としてuspto-grants-1984_10
HRID 1957083 の反応式
HRID 1957083反応物としてuspto-grants-1998_07

化合物ノート

読み込み中…

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その他の操作
ノートを作成反応を作成見積依頼を出す
DTXCID0029769600-151-8trisodium;phosphate;dodecahydrateMFCD00149198H24Na3O16PPhosphoric acid, sodium salt, hydrate (1:3:12)Trisodium phosphate (tert) dodecahydrateNa3PO4.12H2O
O.O.O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[Na+].[O-]P([O-])([O-])=O
LogP
-2.148 · -2.148 (est)
CAS データベース
10101 · 10101-89-0(CAS DataBase Reference)
EPAの化学物質情報
Trisodium phosphate dodecahydrate (10101-89-0)
Absorption
0.023 at · ≤0.023 at 280 in H2O at 0.5M≤0.035 at 260 in H2O at 0.5M

化学的性質

化学的特性colorless or white crystal(s); used to soften water, as a detergent and metal cleaner [MER06] [HAW93] [STR93]

Adverse EffectsDermatotoxin - Skin burns.

安全データ

wgk
1
tsca
Yes
rtecs
TC9575000
ridadr
UN 3262 8/PG 3
毒性
LD50 orally in Rabbit: 7400 mg/kg
hs_code
28352300
risk_code
34-35-36/38
hazard_code
C
safety_code
26-36/37/39-45-24/25
hazard_class
8
packing_group
III
Hazard Classifications
Eye Irrit. 2Skin Irrit. 2STOT SE 3
ストレージクラス
8A - Combustible corrosive hazardous materials

使用Sodium phosphate tribasic dodecahydrate is often used in the formulation of various buffers.

一般的な説明Sodium phosphate tribasic dodecahydrate is a hydrated trisodium salt of phosphoric acid. It is widely used in various water treatment methods.

調製方法

純化方法It crystallises from warm dilute aqueous NaOH (1mL/g) on cooling to 0o.

上流・下流製品情報

上流原料

Caustic Soda(liquid)30%-48%Phosphate rock powderFood grade phosphoric acidりん酸リン鉱石Ferric chloride湿式リン酸水酸化ナトリウム硫酸水素炭酸ナトリウム

下流製品

Metal cleaner5-Butylpyridine-2-carbonitrileリグニンスルホン酸カルシウムフザリン酸Filth removerリグニンスルホン酸ナトリウム