Ethylene glycol dimethacrylate → 9-Ethenylcarbazole;oxiran-2-ylmethyl 2-methylprop-2-enoate

HRID 1633392

反応式

HRID 1633392 の反応式
S(OOS([O-])(=O)=O)([O-])(=O)=O.[K+].[K+].O.O.O.O.O.O.O.O.O.O.O.O.P([O-])([O-])([O-])=O.[Na+].[Na+].[Na+].S([O-])(O[CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][CH2:47][CH3:48])(=O)=O.[Na+].C=CC1C=CC=CC=1.[C:59]([O:64][CH2:65][CH2:66][O:67][C:68](=O)C(C)=C)(=[O:63])[C:60]([CH3:62])=[CH2:61].C(C1C2[NH:86][C:85]3C(=CC=C[CH:84]=3)C=2C=CC=1)=C>ClCCl.O>[CH2:84]=[CH:85][N:86]1[C:48]2[C:43](=[CH:44][CH:45]=[CH:46][CH:47]=2)[C:42]2[C:37]1=[CH:38][CH:39]=[CH:40][CH:41]=2.[CH3:62][C:60]([C:59]([O:64][CH2:65][CH:66]1[O:67][CH2:68]1)=[O:63])=[CH2:61]

参加物

9

反応物 6

HCID 7355Ethylene glycol dimethacrylateHCID 7501StyreneHCID 24412Potassium PersulfateHCID 61473Trisodium phosphate dodecahydrateHCID 3423265Sodium Lauryl SulfateHCID 15114296Pavettine

生成物 1

HCID 1317130799-Ethenylcarbazole;oxiran-2-ylmethyl 2-methylprop-2-enoate

試薬・触媒・溶媒 2

HCID 962Water溶媒HCID 6344Dichloromethane溶媒

実験手順

A 300-mL roundbottomed flask, equipped with a distillation head and a mechanical stirrer, is utilized. 200 mL of water containing 0.5 g of potassium persulfate, 0.5 g of trisodium phosphate dodecahydrate, and 1.5 g of sodium dodecyl sulfate are heated to 70° C. under a nitrogen atmosphere. A seed emulsion is formed by adding 4.5 mL of styrene and 0.5 mL of ethylene glycol dimethacrylate. After 30 min the seed emulsion has a particle size of 0.021 μm and pH of 8.5. A solution of 20 g of vinyl carbazole and one gram of "Aerosol" OT-100 in 10 mL of dichloromethane is then added at a rate of 0.1 mL/min. The dichloromethane is removed by distillation as soon as it is added. After the core emulsion is complete, 0.1 g of potassium persulfate in 10 mL of water is added, and then 2.5 mL of glycidyl methacrylate is added at a feed rate of 0.1 mL/min. 45 min is allowed for the polymerization. The final particle size is 0.041 μm. The final solids content is 10.5%.

後処理

  1. customequipped with a distillation head and a mechanical stirrer
  2. customA seed emulsion is formed
  3. customThe dichloromethane is removed by distillation as soon as it
  4. additionis added
  5. addition0.1 g of potassium persulfate in 10 mL of water is added
  6. addition2.5 mL of glycidyl methacrylate is added at a feed rate of 0.1 mL/min
  7. custom45 min is allowed for the polymerization

出典と根拠

ORDレコード
ord-0e75d605343d42318e460d24bde19f7b
出典データセット
uspto-grants-1984_10
特許番号
US04480042

関連ノート

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