マンガン(II)ジニトラート

Manganese nitrate appears as a white crystalline solid. Denser than water. May ignite on contact with organic matter. Contact may irritate skin, eyes and mucous membranes. May be toxic by ingestion. Used to make other chemicals.

Large Crystals; Liquid

Colorless hygroscopic solid; [Merck Index] White crystals; [CAMEO] 50% Aqueous solution: Pink liquid with an acidic odor; [Alfa Aesar MSDS]

This chemical does not meet GHS hazard criteria for 0.6% (2 of 310) of reports.

Danger

H272 (89%): May intensify fire; oxidizer [Danger Oxidizing liquids; Oxidizing solids]

P210, P220, P260, P264, P264+P265, P270, P273, P280, P301+P317, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P319, P321, P330, P363, P370+P378, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 310 reports by companies from 26 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

Chemical: Nitric acid, manganese(2+) salt

Nitric acid, manganese(2+) salt (2:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Nitric acid, manganese(2+) salt (2:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 11-08-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/13480

Nitric acid, manganese(2+) salt: HSNO Approval: HSR001332 Approved with controls

Excerpt from ERG Guide 140 [Oxidizers]:

CAUTION: Ammonium nitrate products may explode if involved in fire or contaminated with hydrocarbons (fuels), organic matter, other contaminants or when hot molten and contained. Treat as an explosive (GUIDE 112).

Excerpt from ERG Guide 140 [Oxidizers]:

· Inhalation, ingestion or contact (skin, eyes) with vapors or substance may cause severe injury, burns or death.

A skin and eye irritant; Toxic by ingestion; May ignite in contact with organic matter or explode in contact with fuels; [CAMEO] 50% Aqueous solution: An oxidizer that may cause fire on contact with combustible materials; A skin and strong eye irritant; [Alfa Aesar MSDS] See Manganese and linked occupational diseases. See NITRATES and NITRITES.

Mixtures of metal/nonmetal nitrates with alkyl esters may explode, owing to the formation of alkyl nitrates; mixtures of nitrate with phosphorus, tin (II) chloride, or other reducing agents may react explosively [Bretherick 1979. p. 108-109]. The anhydrous nitrate salt with urea explodes upon heating, [Chem Abs., 1975, 82, 48151].

Manganese nitrate

UN2724

Div 5.1 Oxidizer (49 eCFR § 173.127)

PG III: the degree of danger presented by the material is minor

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· Keep combustibles (wood, paper, oil, etc.) away from spilled material.

Excerpt from ERG Guide 140 [Oxidizers]:

General First Aid:

· Wear positive pressure self-contained breathing apparatus (SCBA).

0.2 [mg/m3], as Mn (inhalable fraction), 0.02 mg/m3, as Mn (respirable fraction)[German Research Foundation (DFG)]

Excerpt from ERG Guide 140 [Oxidizers]:

Immediate precautionary measure

9.8 [mg/m3]

16 [mg/m3]

98 [mg/m3]

Used to produce manganese dioxide, to color ceramics, and as a catalyst; [NJHSFS] Used to make reagent grade manganese dioxide and porcelain colorants; [Merck Index]

Ceramics making [Category: Hobbies]

Fabricated Metal Product Manufacturing

Nitric acid, manganese(2+) salt (2:1): ACTIVE