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マンガン(II)ジニトラート

Manganese nitrate

HCID 61511
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基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
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基本情報

CAS
10377-66-9
標準SMILES
O=[N+]([O-])[O-].O=[N+]([O-])[O-].[Mn+2]
InChIKey
MIVBAHRSNUNMPP-UHFFFAOYSA-N
分子式
MnN2O6
平均分子量
178.95 g/mol
単同位体質量
178.91368082

概要

Manganese nitrate appears as a white crystalline solid. Denser than water. May ignite on contact with organic matter. Contact may irritate skin, eyes and mucous membranes. May be toxic by ingestion. Used to make other chemicals.

名称と識別子

優先名称
Manganese nitrate
IUPAC
manganese(2+) dinitrate
現地名
マンガン(II)ジニトラート
英語名
Manganese nitrate
分子式
MnN2O6
分子量
178.95

名称と別名

Manganese nitrate10377-66-9Manganese dinitrateManganous nitrateManganous dinitrateManganese (II) nitrateMANGANESE(II) NITRATEManganese(2+) nitrateNitric acid, manganese(2+) saltManganese (II) nitrate, anhydrousEINECS 233-828-8MANGANESE NITRATE [MI]
名称をさらに表示
硝酸第一マンガン硝酸マンガン(II)ビス硝酸マンガン(II)マンガン(II)ジニトラート硝酸マンガン硝酸マンガン()六水和物硝酸マンガン(Ⅱ)硝酸マンガン(II) 溶液硝酸マンガン(II), 50% w/w aq. soln.硝酸マンガン(II), 50-52% aqueous solutionMN(NO3)2Manganese nitrate solutionManganese(Ⅱ)nitrate hexahydrateMangandinitratmanganousdinitratemanganese(2+)nitrate
I389H78514DTXSID90890659EC 233-828-8MANGANESE NITRATE (MN(NO3)2)Nitric acid, manganese(2+) salt (2:1)RefChem:809868DTXCID501030962233-828-8

データベース識別子

CAS
10377-66-9
PubChem CID
61511
DTXSID
DTXSID90890659
UNII
I389H78514
EC Number
233-828-8

物性

構造計算による物性補完中

極性表面積
126 Ų
水素結合供与体数
0
水素結合受容体数
6
回転可能結合数
0
重原子数
9
形式電荷
0
複雑度
18.8

実験および物理化学的性質

Chemical ClassesMetals -> Manganese Compounds, Inorganic
Density1.8 @25 °C
Physical Description · 3 件

Manganese nitrate appears as a white crystalline solid. Denser than water. May ignite on contact with organic matter. Contact may irritate skin, eyes and mucous membranes. May be toxic by ingestion. Used to make other chemicals.

Large Crystals; Liquid

Colorless hygroscopic solid; [Merck Index] White crystals; [CAMEO] 50% Aqueous solution: Pink liquid with an acidic odor; [Alfa Aesar MSDS]

物理化学的性質

融点
37 °C · 37°C
沸点
100 °C · 100°C
比重(密度)
1.536 g/mL · 1.536 g/mL at 25 °C
蒸気圧
0 Pa · 0Pa at 20℃
溶解性
very soluble in ethanol
外見
液体
比重
1.5 · 1.5
色
ピンク
水溶解度
溶ける
Merck
13 · 13,5756
InChI
1S/Mn.2NO3/c;2*2-1(3)4/q+2;2*-1
InChIKey

安全と法規制

安全情報は参考情報です。供給元の安全データシート(SDS)、適用法令、専門家による評価に代わるものではありません。

GHS分類

GHS Classification · 6 件

This chemical does not meet GHS hazard criteria for 0.6% (2 of 310) of reports.

Danger

H272 (89%): May intensify fire; oxidizer [Danger Oxidizing liquids; Oxidizing solids]

P210, P220, P260, P264, P264+P265, P270, P273, P280, P301+P317, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P319, P321, P330, P363, P370+P378, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 310 reports by companies from 26 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

危険有害性情報

Regulatory Information · 4 件

Chemical: Nitric acid, manganese(2+) salt

Nitric acid, manganese(2+) salt (2:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Nitric acid, manganese(2+) salt (2:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 11-08-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/13480

Nitric acid, manganese(2+) salt: HSNO Approval: HSR001332 Approved with controls

Other Safety InformationIMAP assessments - Soluble manganese compounds: Human health tier II assessment
DOT LabelOxidizer
Fire Hazards · 2 件

Excerpt from ERG Guide 140 [Oxidizers]:

CAUTION: Ammonium nitrate products may explode if involved in fire or contaminated with hydrocarbons (fuels), organic matter, other contaminants or when hot molten and contained. Treat as an explosive (GUIDE 112).

Health Hazards · 2 件

Excerpt from ERG Guide 140 [Oxidizers]:

化学と産業

用途と製造

Uses · 2 件

Used to produce manganese dioxide, to color ceramics, and as a catalyst; [NJHSFS] Used to make reagent grade manganese dioxide and porcelain colorants; [Merck Index]

Ceramics making [Category: Hobbies]

U.S. Production2023: 400,000 - <550,000 lb
Consumer UsesIntermediate
Industry UsesCatalyst
General Manufacturing Information · 2 件

Fabricated Metal Product Manufacturing

Nitric acid, manganese(2+) salt (2:1): ACTIVE

応用分野 · 4 件

解説硝酸マンガン(Ⅱ)Mn(NO3)2(178.95).種々の水和物が存在するが,六水和物がもっとも普通である.六水和物は炭酸マンガン(Ⅱ)を希硝酸に溶かした水溶液を25.8 ℃ 以下で蒸発すると得られる.淡桃色の単斜晶系結晶.密度1.82 g cm-3(21 ℃).融点25.8 ℃,沸点129.4 ℃(分解).水,エタノールに易溶.無水物も淡桃色の結晶.その他,一,二,三,四水和物が知られている.希土類元素の硝酸塩と複塩をつくりやすい.この性質は希土類元素の分別結晶に利用される.窯業,コンデンサー,薄膜形成材料,触媒,電池材料などに用いられる.

用途触媒,コンデンサー用 (NITE CHRIP)

使用Ceramics, intermediates, catalyst, manganese dioxide.

一般的な説明A white crystalline solid. Denser than water. May ignite on contact with organic matter. Contact may irritate skin, eyes and mucous membranes. May be toxic by ingestion. Used to make other chemicals.

上流・下流製品情報

上流原料

炭酸マンガン(II)マンガン硝酸

下流製品

二酸化マンガン

関連反応

8 件
反応記録を作成
HRID 366286 の反応式
HRID 366286生成物としてuspto-grants-2000_10
HRID 366287 の反応式
HRID 366287生成物としてuspto-grants-2000_10
HRID 1363856 の反応式
HRID 1363856反応物としてuspto-grants-2011_02
HRID 1580422 の反応式
HRID 1580422触媒としてuspto-grants-1976_01
HRID 1594540 の反応式
HRID 1594540生成物としてuspto-grants-2001_09
HRID 1594541 の反応式
HRID 1594541生成物としてuspto-grants-2001_09
HRID 1744005 の反応式
HRID 1744005触媒としてuspto-grants-2006_03
HRID 2374103 の反応式
HRID 2374103生成物としてuspto-grants-2008_12

化合物ノート

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このページの内容基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
その他の操作
ノートを作成反応を作成見積依頼を出す
MIVBAHRSNUNMPP-UHFFFAOYSA-N
SMILES
[Mn++].[O-][N+]([O-])=O.[O-][N+]([O-])=O
CAS データベース
10377 · 10377-66-9(CAS DataBase Reference)
EPAの化学物質情報
Nitric acid, manganese(2+) salt (10377-66-9)

化学的性質

化学的特性Light red liquid

· Inhalation, ingestion or contact (skin, eyes) with vapors or substance may cause severe injury, burns or death.

Hazards Summary · 1 件

A skin and eye irritant; Toxic by ingestion; May ignite in contact with organic matter or explode in contact with fuels; [CAMEO] 50% Aqueous solution: An oxidizer that may cause fire on contact with combustible materials; A skin and strong eye irritant; [Alfa Aesar MSDS] See Manganese and linked occupational diseases. See NITRATES and NITRITES.

DOT ID and Guide2724 140
Reactive GroupNitrate and Nitrite Compounds, Inorganic
Reactivity AlertsStrong Oxidizing Agent
Reactivity Profile · 1 件

Mixtures of metal/nonmetal nitrates with alkyl esters may explode, owing to the formation of alkyl nitrates; mixtures of nitrate with phosphorus, tin (II) chloride, or other reducing agents may react explosively [Bretherick 1979. p. 108-109]. The anhydrous nitrate salt with urea explodes upon heating, [Chem Abs., 1975, 82, 48151].

DOT Hazard Classification · 4 件

Manganese nitrate

UN2724

Div 5.1 Oxidizer (49 eCFR § 173.127)

PG III: the degree of danger presented by the material is minor

Air and Water ReactionsSoluble in water.

安全と保護具

Fire FightingExcerpt from ERG Guide 140 [Oxidizers]:
Accidental Release Measures · 2 件

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· Keep combustibles (wood, paper, oil, etc.) away from spilled material.

First Aid · 2 件

Excerpt from ERG Guide 140 [Oxidizers]:

General First Aid:

Exposure Control and Personal Protection · 2 件

· Wear positive pressure self-contained breathing apparatus (SCBA).

0.2 [mg/m3], as Mn (inhalable fraction), 0.02 mg/m3, as Mn (respirable fraction)[German Research Foundation (DFG)]

Nonfire Spill ResponseExcerpt from ERG Guide 140 [Oxidizers]:
Isolation and Evacuation · 2 件

Excerpt from ERG Guide 140 [Oxidizers]:

Immediate precautionary measure

Threshold Limit Values (TLV)0.02 [mg/m3], as Mn (respirable fraction), 0.1 mg/m3, as Mn (inhalable fraction)
Protective Action Criteria (PAC) · 3 件

9.8 [mg/m3]

16 [mg/m3]

98 [mg/m3]

Personal Protective Equipment (PPE)Excerpt from ERG Guide 140 [Oxidizers]:
Emergency Response Planning GuidelinesSmall Fire
Immediately Dangerous to Life or Health (IDLH)500 mg Mn/m3 (NIOSH, 2024)

毒性情報

Adverse EffectsNeurotoxin - Parkinsonism

安全データ

wgk
1
tsca
TSCA listed
ridadr
UN 2724
hs_code
28342990
risk_code
8-34-40-36/37/38-36/38-20
hazard_code
O,C,Xn,Xi
safety_code
17-26-27-36/37/39-45-36
hazard_class
5.1
packing_group
III
Hazard Classifications
Acute Tox. 4 OralEye Dam. 1Met. Corr. 1Ox. Liq. 2Skin Corr. 1CSTOT RE 2 Inhalation
ストレージクラス
5.1B - Oxidizing hazardous materials
マンガン酸リチウム
プロピオン酸デプロドン
硝酸マンガン(II)·4水和物